Novel Terthiophene-Substituted Fullerene Derivatives as Easily Accessible Acceptor Molecules for Bulk-Heterojunction Polymer Solar Cells

Nisic Filippo; Colombo Alessia; Dragonetti Claudia; Cominetti Alessandra; Pellegrino Andrea; Perin Nicola; Po Riccardo; Tacca Alessandra

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Novel Terthiophene-Substituted Fullerene Derivatives as Easily Accessible Acceptor Molecules for Bulk-Heterojunction Polymer Solar Cells

机译：新型的对噻吩取代的富勒烯衍生物作为本体异质结聚合物太阳能电池的易获得受体分子

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Five fulleropyrrolidines and methanofullerenes, bearing one or two terthiophene moieties, have been prepared in a convenient way and well characterized. These novel fullerene derivatives are characterized by good solubility and by better harvesting of the solar radiation with respect to traditional PCBM. In addition, they have a relatively high LUMO level and a low band gap that can be easily tuned by an adequate design of the link between the fullerene and the terthiophene. Preliminary results show that they are potential acceptors for the creation of efficient bulk-heterojunction solar cells based on donor polymers containing thiophene units.

机译：已经以方便的方式制备了五个具有一个或两个叔噻吩基团的全吡咯烷和甲基富勒烯。这些新颖的富勒烯衍生物的特点是具有良好的溶解性，并且相对于传统的PCBM具有更好的太阳辐射捕获能力。另外，它们具有相对较高的LUMO能级和低带隙，可以通过富勒烯与对噻吩之间的键的适当设计容易地调节。初步结果表明，它们是潜在的受体，可用于基于含噻吩单元的供体聚合物创建高效的体-异质结太阳能电池。

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《International Journal of Photoenergy》 |2014年第4期|共10页
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Nisic Filippo; Colombo Alessia; Dragonetti Claudia; Cominetti Alessandra; Pellegrino Andrea; Perin Nicola; Po Riccardo; Tacca Alessandra;
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1. Novel Terthiophene-Substituted Fullerene Derivatives as Easily Accessible Acceptor Molecules for Bulk-Heterojunction Polymer Solar Cells [J] . Nisic Filippo, Colombo Alessia, Dragonetti Claudia, International Journal of Photoenergy . 2014,第Pta4期

机译：新型的对噻吩取代的富勒烯衍生物作为本体异质结聚合物太阳能电池的易获得受体分子
2. Effect of acceptor strength in new acceptor donor acceptor-type molecules on their miscibility with donor polymers for bulk-heterojunction fullerene-free solar cells [J] . Park Seo Yeon, Park Gi Eun, Choi Suna, Dyes and Pigments . 2017,第期

机译：新受体供体型分子对富含富勒环芳烯太阳能电池的供体聚合物的混溶性的影响
3. Alkyl substituted [6,]1-thienyl-C_(61)-butyric acid methyl esters: easily accessible acceptor materials for bulk-heterojunction polymer solar cells [J] . Huiyu Zhao, Xiaoyang Guo, Hongkun Tian Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology . 2010,第15期

机译：烷基取代的[6，] 1-噻吩基-C_（61）-丁酸甲酯：易于使用的本体异质结聚合物太阳能电池的受体材料
4. C_(70) DERIVATIVES AS ELECTRON ACCEPTORS IN POLYMER-FULLERENE SOLAR CELLS [C] . P. Morvillo, E. Bobeico European Photovoltaic Solar Energy Conference . 2009

机译：C_（70）衍生物作为聚合物 - 富勒烯太阳能电池中的电子受体
5. Device Physics and Recombination in Polymer:Fullerene Bulk-Heterojunction Solar Cells [D] . Hawks, Steven Aaron 2015

机译：聚合物中的装置物理与复合：富勒烯本体-异质结太阳能电池
6. Recent Advances in Non-Fullerene Acceptors of the IDIC/ITIC Families for Bulk-Heterojunction Organic Solar Cells [O] . Giacomo Forti, Andrea Nitti, Peshawa Osw, 2020

机译：诸如批量交联有机太阳能电池的IDIC / ITIC系列非富勒烯受体的最新进展
7. Design and synthesis of soluble dibenzosuberane-substituted fullerene derivatives for bulk-heterojunction polymer solar cells [O] . Kolemen, S., Cakmak, Y., Ozdemir, T., 2014

机译：可溶性二苯并辛基取代的设计与合成本体异质结聚合物的富勒烯衍生物太阳能电池

Novel Terthiophene-Substituted Fullerene Derivatives as Easily Accessible Acceptor Molecules for Bulk-Heterojunction Polymer Solar Cells

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