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Annular Extrudate Swell of a Fluoropolymer Melt

机译:含氟聚合物熔体的环形挤出物溶胀

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摘要

Annular extrudate swell is studied for a fluoropolymer (FEP) melt using a tubular die. The rheological data of the melt have been fitted using (i) a viscous model (Cross) and (ii) a visco-elastic one (the Kaye - Bernstein, Kearsley, Zapas/Papanasta-siou, Scriven, Macosko or K-BKZ/PSM model). Numerical simulations have been undertaken to study the extrudate swell of the FEP melt in an annular die. Compressibility, thermal and pressure effects on viscosity, and slip at the wall were taken into account. In all cases, slip at the wall is the dominant contribution reducing the swelling when compared with corresponding no-slip simulations. The viscous (Cross) simulations show that the swell decreases with increasing apparent shear rate, which is opposite to what happens in the extrusion of vis-coelastic melts. On the other hand, the viscoelastic (K-BKZ) simulations correctly obtain increasing swelling with increasing shear (flow) rates. It was found that due to the mild visco-elasticity of FEP and its severe slip at the wall the swelling of this melt is relatively small, reaching values of about 20% for a wide range of apparent shear rates, exceeding 5000 s~(-1) . This is corroborated by experimental observations.
机译:使用管状模头研究含氟聚合物(FEP)熔体的环形挤出物溶胀。熔体的流变数据已使用(i)粘性模型(Cross)和(ii)粘弹性模型(Kaye-Bernstein,Kearsley,Zapas / Papanasta-siou,Scriven,Macosko或K-BKZ / PSM模型)。已经进行了数值模拟,以研究环形模具中FEP熔体的挤出胀大。考虑了可压缩性,热和压力对粘度的影响以及壁的滑移。在所有情况下,与相应的无滑移仿真相比,壁滑是减少膨胀的主要作用。粘性(交叉)模拟表明,溶胀随表观剪切速率的增加而减小,这与粘弹性熔体的挤出过程相反。另一方面,粘弹性(K-BKZ)模拟可以正确地获得随着剪切(流动)速率增加而增加的溶胀。已经发现,由于FEP的粘弹性适中,并且在壁上严重滑移,因此该熔体的溶胀相对较小,在超过5000 s〜(- 1)。实验观察证实了这一点。

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