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首页> 外文期刊>International Journal of Photoenergy >Sensitization of Perovskite Strontium Stannate SrSnO3 towards Visible-Light Absorption by Doping
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Sensitization of Perovskite Strontium Stannate SrSnO3 towards Visible-Light Absorption by Doping

机译:掺杂钙钛矿锶酸锶SrSnO3对可见光吸收的敏化

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摘要

Perovskite strontium stannate SrSnO3 is a promising photocatalyst. However, its band gap is too large for efficient solar energy conversion. In order to sensitize SrSnO3 toward visible-light activities, the effects of doping with various selected cations and anions are investigated by using hybrid density functional calculations. Results show that doping can result in dopant level to conduction band transitions which lie lower in energy compared to the original band gap transition. Therefore, it is expected that doping SrSnO3 can induce visible-light absorption.
机译:钙钛矿锶酸锶SrSnO3是有前途的光催化剂。然而,其带隙对于有效的太阳能转换而言太大。为了使SrSnO3对可见光活动敏感,通过使用混合密度泛函计算研究了掺杂各种选定阳离子和阴离子的影响。结果表明,与原始带隙跃迁相比,掺杂可以导致掺杂剂能级到导带跃迁,其能量更低。因此,预期掺杂SrSnO3会引起可见光吸收。

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