Solvent reorganization energies in excited-state electron-transfer reactions. Oxidative quenching of the MLCT excited states of Ru(II)-diimine complexes

Crowley CE.; Hoffman MZ.; Clark CD.

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Solvent reorganization energies in excited-state electron-transfer reactions. Oxidative quenching of the MLCT excited states of Ru(II)-diimine complexes

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Solvent reorganization energies in excited-state electron-transfer reactions. Oxidative quenching of the MLCT excited states of Ru(II)-diimine complexes

机译：激发态电子转移反应中的溶剂重组能。 Ru（II）-二亚胺配合物MLCT激发态的氧化猝灭

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The reorganization energy (lambda) for the oxidative quenching of *RuL32+ (L = phen, 5,6-Me(2)phen, 5-Clphen) by MV2+ in aqueous solutian is in the order NaClO4 < NaI < NaBr < NaCl < NaF < NaH2PO4. In each of the electrolyte solutions, the Clphen and Me(2)phen complexes exhibited the lowest and highest values of lambda, respectively. The presence of electron-withdrawing and -donating substituents on the ligand affect the structure of the solvent cage and the energetics of solvent reorganization. [References: 31]

机译：MV2 +在水溶液中对* RuL32 +（L = phen，5,6-Me（2）phen，5-Clphen）进行氧化猝灭的重组能（λ）的顺序为NaClO4

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |1998年第21期|共3页
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Crowley CE.; Hoffman MZ.; Clark CD.;
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正文语种 eng
中图分类化学;
关键词
Transfer rates; Dependence; Ru(ii);

机译：transfer rates;dependence;Ru(II);
入库时间 2022-08-18 10:42:47

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1. Solvent reorganization energies in excited-state electron-transfer reactions. Oxidative quenching of the MLCT excited states of Ru(II)-diimine complexes [J] . Crowley CE., Hoffman MZ., Clark CD. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第21期

机译：激发态电子转移反应中的溶剂重组能。 Ru（II）-二亚胺配合物MLCT激发态的氧化猝灭
2. Mechanism of quenching by oxygen of the excited states of ruthenium(II) complexes in aqueous media. Solvent isotope effect and photosensitized generation of singlet oxygen, O-2((1)Delta(g)), by [Ru(diimine)(CN)(4)](2-) complex ions [J] . Abdel-Shafi AA, Ward MD, Schmidt R Dalton transactions: An international journal of inorganic chemistry . 2007,第24期

机译：水性介质中钌（II）配合物激发态的氧猝灭机理。 [Ru（二亚胺）（CN）（4）]（2-）络合离子的溶剂同位素效应和单态氧O-2（（1）Delta（g））的光敏生成
3. Defect Density-Dependent Electron Injection from Excited-State Ru(II) Tris-Diimine Complexes into Defect-Controlled Oxide Semiconductors [J] . Nishioka Shunta, Yamazaki Yasuomi, Okazaki Megumi, The journal of physical chemistry, C. Nanomaterials and interfaces . 2019,第46期

机译：从激发态Ru（II）Tris-二亚胺复合物中的缺陷密度依赖电子注入到缺陷控制的氧化物半导体中
4. IRON-NICKEL LAYERED DOUBLE HYDROXIDE COMBINED WITH RU(II)-DIIMINE AS VISIBLE LIGHT PHOTOSENSITIZER IN WATER OXIDATION ELECTROCATALYSIS [C] . D. F. Sranko, Zs. E. Horvath, M. Chamam Joint Conference on Chemisty . 2016

机译：铁 - 镍层双氢氧化物与Ru（II）结合Ru（II） - 作为可见光光敏剂在水氧化电催化中
5. I. Ground-state association between phenothiazine and tris(diimine)ruthenium(II) complexes: Its role in highly efficient photoinduced charge separation. II. Ligand modifications of cobalt complexes to increase efficiency of electron-transfer mediators in dye-sensitized solar cells [D] . Weber, John 2012

机译：一，吩噻嗪与三（二亚胺）钌（II）配合物之间的基态缔合：在高效光诱导电荷分离中的作用。二。钴配合物的配体修饰，以提高染料敏化太阳能电池中电子转移介体的效率
6. Surface-Bound Ruthenium Diimine Organometallic Complexes:Excited-State Properties [O] . Geoffrey Abbott, Robert Brooks, Edward Rosenberg, -1

机译：表面结合的钌二亚胺有机金属配合物：激发态性质
7. Solvent Reorganization Energy in Excited-State Electron-Transfer Reactions. Quenching and Geminate-Pair Back Electron Transfer [O] . Catherine D. Clark, Morton Z. Hoffman 1997

机译：溶剂重组能量在激发状态电子转移反应中。淬火和生长对电子转移
8. Solvent Dependence of Metal-to-Ligand Charge-Transfer Transitions. Evidence for Initial Electron Localization in MLCT Excited States of 2,2'-Bipyridine Complexes of Ru(II) And Os(II) [R] . Kober, E. M., Sullivan, B. P., Meyer, T. J. 1983

机译：金属与配体电荷转移跃迁的溶剂依赖性。 Ru（II）和Os（II）2,2'-联吡啶配合物mLCT激发态初始电子定位的证据

Solvent reorganization energies in excited-state electron-transfer reactions. Oxidative quenching of the MLCT excited states of Ru(II)-diimine complexes

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