Synthesis and Characterization of an AL_60~(3-) Cluster with 51 Naked Al Atoms: Analogies and Differences to the Previously Characterized Al_77~(2-) Cluster

H.Kohnlein; A.Purath; C.Klemp

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Synthesis and Characterization of an AL_60~(3-) Cluster with 51 Naked Al Atoms: Analogies and Differences to the Previously Characterized Al_77~(2-) Cluster

机译：具有51个裸Al原子的AL_60〜（3-）团簇的合成与表征：与先前表征的Al_77〜（2-）团簇的类比和区别

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A disproportionation process of a metastable AlCl solution with a simultaneous ligand exchange-Cl is substituted by N(SiMe_3)_2-leads to a [Al_69{N(SiMe_3)_2}_18]~(3-) cluster compound that can be regarded as an intermediate on the way to bulk metal formation.

机译：具有同时配体交换-Cl的亚稳态AlCl溶液的歧化过程被N（SiMe_3）_2取代，导致[Al_69 {N（SiMe_3）_2} _18]〜（3-）簇化合物形成大块金属的中间产物。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2001年第19期|共9页
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H.Kohnlein; A.Purath; C.Klemp;
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1. Synthesis and Characterization of an AL_60~(3-) Cluster with 51 Naked Al Atoms: Analogies and Differences to the Previously Characterized Al_77~(2-) Cluster [J] . H.Kohnlein, A.Purath, C.Klemp Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第19期

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Synthesis and Characterization of an AL_60~(3-) Cluster with 51 Naked Al Atoms: Analogies and Differences to the Previously Characterized Al_77~(2-) Cluster

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