• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >SYNTHETIC AND STRUCTURAL STUDIES OF GALLIUM-PHOSPHORUS, GALLIUM-ARSENIC, AND INDIUM-PHOSPHORUS COMPOUNDS WITH CHROMOPHORIC SUBSTITUENTS
【24h】

SYNTHETIC AND STRUCTURAL STUDIES OF GALLIUM-PHOSPHORUS, GALLIUM-ARSENIC, AND INDIUM-PHOSPHORUS COMPOUNDS WITH CHROMOPHORIC SUBSTITUENTS

机译：含镓取代基的镓-磷，镓-砷和铟-磷化合物的合成和结构研究

获取原文
获取原文并翻译 | 示例
       
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Seven group 13/15 four-membered-ring compounds of the general type [R2ME-t-Bu-2](2) bearing the chromophoric substituents (R) vinyl, allyl, and benzyl have been synthesized by treatment of t-Bu2PLi or t-Bu2AsLi with the appropriate gallium or indium chloride, R2MCl (prepared in situ), in Et2O solution: 3 (R = vinyl, M = Ga, E = P); 4 (R = vinyl, M = In, E = P); 5 (R = allyl, M = In, E = P); 6 (R = allyl, M = Ga, E As); 7 (R = benzyl, M = In, E P); 8 (R = benzyl, M = Ga, E = As); 10 (R = vinyl, M = Ga, E = As). The partially substituted derivative [(vinyl)ClGaAs-t-Bu-2](2) (9) was prepared by a similar one-pot procedure. All eight new compounds were characterized by X-ray crystallography, NMR, and mass spectroscopy. Compounds 3-8 absorb light at relatively long wavelengths with cutoffs ranging from similar to 300 nm for the vinyl-substituted compounds to similar to 330 nm for the corresponding allyl- and benzyl-substituted derivatives. [References: 38]
机译：通过处理t-Bu2PLi或t-Bu2PLi，已合成了带有发色取代基（R）乙烯基，烯丙基和苄基的七个总类型为[R2ME-t-Bu-2]（2）的七个13/15四元环化合物。在Et2O溶液中的t-Bu2AsLi与适当的镓或铟氯化物R2MCl（原位制备）：3（R =乙烯基，M = Ga，E = P）; 4（R =乙烯基，M = In，E = P）; 5（R ＝烯丙基，M ＝ In，E ＝ P）; 6（R =烯丙基，M = Ga，E As）; 7（R =苄基，M = In，EP）; 8（R =苄基，M = Ga，E = As）; 10（R ＝乙烯基，M ＝ Ga，E ＝ As）。通过类似的一锅法制备部分取代的衍生物[（乙烯基）ClGaAs-t-Bu-2]（2）（9）。所有八个新化合物均通过X射线晶体学，NMR和质谱进行了表征。化合物3-8吸收相对较长波长的光，其截止范围对于乙烯基取代的化合物而言约为300nm，对于相应的烯丙基和苄基取代衍生物而言约为330nm。 [参考：38]

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号