Synthesis of neutral iridium(III) and rhodium(III) complexes with the proligands (Pr2P)-P-i(C6H4-SH-2) [pr(i)PSH](1); PhP(C6H4-SH-2)(2) [phPS(2)H(2)] and PhP(C2H4SH)(2) [ePS(2)H(2)](3). The X-ray crystal structures of [Ir(pr(i)PS)(3)] and [Rh(H)(phPS

Morales-Morales D.; Rodriguez-Morales S.; Dilworth JR.; Sousa-Pedrares A. Zheng YF.

首页> 外文期刊>Inorganica Chimica Acta >Synthesis of neutral iridium(III) and rhodium(III) complexes with the proligands (Pr2P)-P-i(C6H4-SH-2) [pr(i)PSH](1); PhP(C6H4-SH-2)(2) [phPS(2)H(2)] and PhP(C2H4SH)(2) [ePS(2)H(2)](3). The X-ray crystal structures of [Ir(pr(i)PS)(3)] and [Rh(H)(phPS

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Synthesis of neutral iridium(III) and rhodium(III) complexes with the proligands (Pr2P)-P-i(C6H4-SH-2) [pr(i)PSH](1); PhP(C6H4-SH-2)(2) [phPS(2)H(2)] and PhP(C2H4SH)(2) [ePS(2)H(2)](3). The X-ray crystal structures of [Ir(pr(i)PS)(3)] and [Rh(H)(phPS

机译：合成具有配体（Pr2P）-P-i（C6H4-SH-2）[pr（i）PSH]（1）的中性铱（III）和铑（III）配合物; PhP（C6H4-SH-2）（2）[phPS（2）H（2）]和PhP（C2H4SH）（2）[ePS（2）H（2）]（3）。 [Ir（pr（i）PS）（3）]和[Rh（H）（phPS）的X射线晶体结构

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The reactivity of the hybrid phosphorus-sulfur proligands pr(i)PSH, phPS(2)H(2) and ePS(2)H(2) with iridium and rhodium precursors has been explored. By reacting IrCl3 with pr(i)PSH in the presence of NEt3 as base, the octahedral Ir(111) specie [Ir(pr(i)PS)(3)] was obtained and its crystal structure determined. Reactions of the potentially tridentated proligands phPS(2)H(2) and ePS(2)H(2) with trans-[MF(CO)(PPh3)(2)] (M = Rh and Ir) were also investigated. Complexes of general formula [M(H)(phPS(2))(CO)(PPh3)] were obtained with phPS(2)H(2). A single crystal X-ray structure determination for [Rh(H)(PhPS2)(CO)(PPh3)] showed the complex to be octahedral. Reactions with the aliphatic proligand ePS(2)H(2) afforded analogous species to those with phPS(2)H(2). (C) 2002 Elsevier Science B.V. All rights reserved. [References: 53]

机译：已探究了杂化磷硫配体pr（i）PSH，phPS（2）H（2）和ePS（2）H（2）与铱和铑前体的反应性。在NEt3为碱的存在下，通过使IrCl3与pr（i）PSH反应，获得八面体Ir（111）物种[Ir（pr（i）PS）（3）]，并确定其晶体结构。还研究了潜在的三齿配体phPS（2）H（2）和ePS（2）H（2）与反式-[MF（CO）（PPh3）（2）]（M = Rh和Ir）的反应。与phPS（2）H（2）获得了通式[M（H）（phPS（2））（CO）（PPh3）]的配合物。 [Rh（H）（PhPS2）（CO）（PPh3）]的单晶X射线结构测定表明该络合物为八面体。与脂族配体ePS（2）H（2）的反应提供了类似于phPS（2）H（2）的种类。（C）2002 Elsevier Science B.V.保留所有权利。 [参考：53]

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《Inorganica Chimica Acta》 |2002年第0期|共7页
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Morales-Morales D.; Rodriguez-Morales S.; Dilworth JR.; Sousa-Pedrares A. Zheng YF.;
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中图分类生物体其他化学成分;无机化学;
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1. Synthesis of neutral iridium(III) and rhodium(III) complexes with the proligands (Pr2P)-P-i(C6H4-SH-2) [pr(i)PSH](1); PhP(C6H4-SH-2)(2) [phPS(2)H(2)] and PhP(C2H4SH)(2) [ePS(2)H(2)](3). The X-ray crystal structures of [Ir(pr(i)PS)(3)] and [Rh(H)(phPS [J] . Morales-Morales D., Rodriguez-Morales S., Dilworth JR., Inorganica Chimica Acta . 2002,第0期

机译：合成具有配体（Pr2P）-P-i（C6H4-SH-2）[pr（i）PSH]（1）的中性铱（III）和铑（III）配合物; PhP（C6H4-SH-2）（2）[phPS（2）H（2）]和PhP（C2H4SH）（2）[ePS（2）H（2）]（3）。 [Ir（pr（i）PS）（3）]和[Rh（H）（phPS）的X射线晶体结构
2. Synthesis of a neutral S-P-S pincer Pd(II) complex with the proligand PhP(C6H4-SH-2)(2) [phPS(2)H(2)]. The X-ray crystal structure of [Pd(phPS(2))(PPh3)] [J] . Gomez-Benitez V., Hernandez-Ortega S., Morales-Morales D. Inorganica Chimica Acta . 2003,第0期

机译：具有配体PhP（C6H4-SH-2）（2）[phPS（2）H（2）]的中性S-P-S钳夹Pd（II）配合物的合成。 [Pd（phPS（2））（PPh3）]的X射线晶体结构
3. Synthesis of a neutral S-P-S pincer Pd(II) complex with the proligand PhP(C6H4-SH-2)(2) [phPS(2)H(2)]. The X-ray crystal structure of [Pd(phPS(2))(PPh3)] [J] . Gomez-Benitez V., Hernandez-Ortega S., Morales-Morales D. Inorganica Chimica Acta . 2003,第0期

机译：具有配体PhP（C6H4-SH-2）（2）[phPS（2）H（2）]的中性S-P-S钳夹Pd（II）配合物的合成。 [Pd（phPS（2））（PPh3）]的X射线晶体结构
4. Synthesis, protonation and x-ray crystal structures of Ni(SC_6H_3Me_2-2,6){triphos}BPh_4 and Ni(SC_6H_4R-2){triphos}BPh4 {R = Me, MeO Or Cl; triphos = PhP(Ph_2PCH_2CH_2)_2}: Unusual structure when R = Cl [C] . Thaer M. M. Al-Rammahi, William Clegg, Michael Probert, International Conference on Applied Science and Technology . 2019

机译：ni（sc_6h_3me_2-2,6）{triphos} bph_4和ni（sc_6h_4r-2）{triphos} bph4 {r = me，meo或cl的合成，质子化和X射线晶体结构; triphos = php（ph_2pch_2ch_2）_2}：当r = cl时异常结构
5. Photophysical properties of ortho-metalated monomeric and dimeric complexes containing rhodium(III) and iridium(III) metal centers. [D] . Marshall, Jason Alexander. 2002

机译：含铑（III）和铱（III）金属中心的邻金属化单体和二聚配合物的光物理性质。
6. DNA Binding Test X-Ray Crystal Structure Spectral Studies TG-DTA and Electrochemistry of CoX2(dmdphphen) (Dmdphphen Is 29-Dimethyl-47-diphenyl-110-phenanthroline X = Cl and NCS) Complexes [O] . Mousa Al-Noaimi, Mohammed Suleiman, Hany W. Darwish, 2014

机译：DNA结合测试X射线晶体结构光谱研究TG-DTA和CoX2（dmdphphen）的电化学（Dmdphphen是29-二甲基-47-二苯基-110-菲咯啉X = Cl和NCS）复合体
7. DNA Binding Test, X-Ray Crystal Structure, Spectral Studies, TG-DTA, and Electrochemistry of CoX2(dmdphphen) (Dmdphphen Is 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, X = Cl, and NCS) Complexes [O] . Al-Noaimi Mousa, Suleiman Mohammed, Darwish Hany W., 2014

机译：DNA结合测试，X射线晶体结构，光谱研究，TG-DTA和CoX2（dmdphphen）的电化学（Dmdphphen是2,9-二甲基-4,7-二苯基-1,10-菲咯啉，X = Cl和NCS）复合体
8. Cyclic Polysilanes XIII. Ring Closure Reactions of Alpha, Omega-Dichloropermethylpolysilanes: The Preparation of Heterocyclic Phenylphosphapermethylsilanes(PhP)m(SiMe2)n. [R] . Oakley, R. T., Stanislawski, D. A., West, R. 1978

机译：环状聚硅烷XIII。 α，ω-二氯甲基聚硅烷的环闭合反应：杂环苯基磷杂甲基硅烷（php）m（sime2）n的制备。

Synthesis of neutral iridium(III) and rhodium(III) complexes with the proligands (Pr2P)-P-i(C6H4-SH-2) [pr(i)PSH](1); PhP(C6H4-SH-2)(2) [phPS(2)H(2)] and PhP(C2H4SH)(2) [ePS(2)H(2)](3). The X-ray crystal structures of [Ir(pr(i)PS)(3)] and [Rh(H)(phPS

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