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Electrogenerated poly(chiral dicarbazole) films for the reagentless grafting of enzymes

机译:电生成的聚(手性二咔唑)薄膜,用于酶的无试剂接枝

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New chiral dicarbazole derivatives functionalized by N-hydroxysuccinimide and pentafluorophenoxy groups have been synthesized and electrochemically characterized. Upon oxidative electropolymerization of these monomers in organic electrolytes electroactive poly(dicarbazole) films were formed on platinum electrodes. The subsequent chemical grafting of glucose oxidase on the poly(dicarbazole) films was easily performed by immersion in an enzymatic aqueous solution. The amperometric response of the resulting biosensors to glucose has been studied at 0.6 V vs. aqueous saturated calomel electrode. [References: 34]
机译:已合成并通过电化学方法表征了由N-羟基琥珀酰亚胺和五氟苯氧基官能化的新型手性二咔唑衍生物。这些单体在有机电解质中进行氧化电聚合后,在铂电极上形成了电活性聚二咔唑薄膜。将葡萄糖氧化酶随后化学接枝到聚二咔唑膜上很容易,方法是将其浸入酶促水溶液中。已在相对于含水甘汞电极0.6 V的条件下研究了所得生物传感器对葡萄糖的安培响应。 [参考:34]

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