Ion transfer of reduced Keggin-type heteropolymolybdate anions at the nitrobenzene/water interface and its relevance to their antitumoral activities

Ding J.; Osakai T.

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Ion transfer of reduced Keggin-type heteropolymolybdate anions at the nitrobenzene/water interface and its relevance to their antitumoral activities

机译：还原的Keggin型杂多钼酸根阴离子在硝基苯/水界面处的离子转移及其与其抗肿瘤活性的关系

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The transfer of two-electron reduced Keggin anions (alpha- and beta-[(PMo2Mo10O40)-Mo-V-O-VI](5-) and alpha-[(SiMo2Mo10O40)-Mo-V-O-VI](6-)) across the nitrobenzene/water interface was studied by cyclic voltammetry. Based on measurements of the ion-transfer potential at various pHs, ionic distribution diagrams were prepared. It was found that the polyanion transfer was usually accompanied by the proton transfer. To confirm the validity of the distribution diagrams, the theoretical simulation of normal-pulse voltammograms was also performed. The ion-transfer potentials of some Keggin-type heteropolymolybdate anions at a physiological pH (7.0) showed an excellent correlation with their antitumoral activities, suggesting a crucial role of their stability in the aqueous solution. [References: 25]

机译：两电子还原的Keggin阴离子（α-和β-[（PMo2Mo10O40）-Mo-VO-VI]（5-）和α-[（SiMo2Mo10O40）-Mo-VO-VI]（6-）的转移通过循环伏安法研究了硝基苯/水的界面。基于在各种pH下的离子转移电势的测量，绘制了离子分布图。发现聚阴离子转移通常伴随有质子转移。为了确认分布图的有效性，还对正脉冲伏安图进行了理论模拟。某些Keggin型杂多钼酸根阴离子在生理pH（7.0）时的离子转移势与其抗肿瘤活性密切相关，表明它们在水溶液中的稳定性至关重要。 [参考：25]

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《Electroanalysis》 |2001年第5期|共8页
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Ding J.; Osakai T.;
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中图分类电化学、电解、磁化学;
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1. Ion transfer of reduced Keggin-type heteropolymolybdate anions at the nitrobenzene/water interface and its relevance to their antitumoral activities [J] . Ding J., Osakai T. Electroanalysis . 2001,第5期

机译：还原的Keggin型杂多钼酸根阴离子在硝基苯/水界面处的离子转移及其与其抗肿瘤活性的关系
2. Ion Transfer of Vanadium-substituted Heteropoly-tungstate Anions at the Nitrobenzene/Water Interface and its Relevance to Their Antiviral Activities [J] . Jie Ding, Toshiyuki Osakai Review of Polarography . 2000,第3a6期

机译：钒取代的杂多钨酸根阴离子在硝基苯/水界面的离子转移及其与抗病毒活性的关系
3. ELECTROCHEMICAL STUDY OF ISOPOLY AND HETEROPOLY ANION TRANSFER ACROSS THE WATER NITROBENZENE INTERFACE .2. VANADIUM-CONTAINING HETEROPOLYTUNGSTATE ANIONS [J] . Wang EK., Wang EB., Wang EK., Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 1995,第1a2期

机译：水-硝基苯界面上同位素和杂原子阴离子转移的电化学研究。含钒杂多态态阴离子
4. X-ray Reflectivity from Neat 2-Heptanone/Water and Nitrobenzene/Water Interfaces and from Nitrobenzene/Water Interfaces Biased by a Common Ion [C] . Guangming Luo, Petr Vanysek, Sai Venkatesh Pingali ECS Meeting . 2003

机译：来自整齐的2-庚酮/水和硝基苯/水界面的X射线反射率，以及由普通离子偏置的硝基苯/水界面
5. Model catalysts of ammonia synthesis and iron -water interfaces: A sum frequency generation vibrational spectroscopic study of solid -gas interfaces and anion photoelectron spectroscopic study of selected anion clusters. [D] . Ferguson, Michael James. 2005

机译：氨合成和铁-水界面的模型催化剂：固-气界面的总频率产生振动光谱研究和选定阴离子簇的阴离子光电子光谱研究。
6. Anion Transfer at a Micro-Water/12-Dichloroethane Interface Facilitated by β-Octafluoro-meso-octamethylcalix4pyrrole [O] . Renfa Cui, Qing Li, Dustin E. Gross, -1

机译：β-八氟-间位-八甲基杯4吡咯促进的微水/ 12-二氯乙烷界面阴离子的转移
7. Determination of the standard Gibbs energies of transfer of cations and anions of amino acids and small peptides across the water nitrobenzene interface. [O] . Gulaboski Rubin, Mirceski Valentin, Scholz Fritz 2003

机译：确定跨硝基苯水界面的氨基酸和小肽的阳离子和离子转移的标准吉布斯能量。
8. Distribution of Oxacyanine Dyes Between Water and Nitrobenzene: Determination of the Partition Constants, Association and Potentials of Transfer of the Dye Cations on Liquid /Liquid Interfaces. [R] . Wiegand, D. H., Vanysek, P. 1989

机译：水和硝基苯之间的Oxacyanine染料的分布：染料阳离子在液/液界面上转移的分配常数，缔合和电位的测定。

Ion transfer of reduced Keggin-type heteropolymolybdate anions at the nitrobenzene/water interface and its relevance to their antitumoral activities

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