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Cyclic voltammetry study of the C-60-EDTA derivative films

机译:C-60-EDTA衍生物薄膜的循环伏安法研究

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摘要

The films of an amphiphilic C-60-EDTA (C(60)EA) and its tetramethyl ester (C60EM), prepared both by drop-coating and Langmuir-Blodgett (LB) technique, were studied by cyclic voltammetry in acetonitrile solutions of tetra-12-butylammonium hexafluorophosphate as the supporting electrolyte. The drop-coated film of C60EM displayed four pairs of redox peaks, which vanished after a few cycles due to the film dissolution. For the LB film of C60EM, three irreversible reduction peaks were observed. Both the drop-coated and the LB film of C(60)EA showed two irreversible reduction peaks. [References: 24]
机译:通过循环伏安法在四乙腈的乙腈溶液中研究了通过滴涂和Langmuir-Blodgett(LB)技术制备的两亲性C-60-EDTA(C(60)EA)及其四甲酯(C60EM)的薄膜-12-丁基六氟磷酸铵为辅助电解质。 C60EM的滴涂膜显示四对氧化还原峰,由于膜溶解,在几个循环后消失。对于C60EM的LB膜,观察到三个不可逆的还原峰。 C(60)EA的滴涂和LB膜均显示了两个不可逆的还原峰。 [参考:24]

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