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Determination of sodium diethyldithiocarbamate in water by anodic voltammetry using a boron-doped diamond electrode

机译:硼掺杂金刚石电极阳极伏安法测定水中的二乙基二硫代氨基甲酸钠

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摘要

An electrochemical study was made of the anodic behavior of sodium diethyldithiocarbamate (DEDTC) using a boron-doped diamond electrode (BDDE) in sodium sulfate supporting electrolyte. This paper presents a new alternative for the electroanalytical determination of DEDTC in protic media, using cyclic voltammetry or chronoamperometry. Linear plots of current vs. concentration correlated with anodic stepwise oxidation were obtained in delimited potential ranges with very good correlation coefficients.
机译:使用硫酸钠支持电解质中的掺硼金刚石电极(BDDE)对二乙基二硫代氨基甲酸钠(DEDTC)的阳极行为进行了电化学研究。本文提出了一种新的替代方法,可以使用循环伏安法或计时安培法对质子介质中的DEDTC进行电分析测定。在限定的电势范围内获得了具有很好的相关系数的,与阳极逐步氧化相关的电流对浓度的线性图。

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