The limits of aqueous hot-wire electrochemistry: Near-critical and supercritical fluids in electrochemical sensors?

Grundler P.; Degenring D.

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The limits of aqueous hot-wire electrochemistry: Near-critical and supercritical fluids in electrochemical sensors?

机译：水热丝电化学的局限性：电化学传感器中的近临界和超临界流体？

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The experimental and theoretical limits of superheat of water in hot-wire electrochemistry were determined. The maximum attainable temperature was ca. 250 degreesC during 5 ms hear pulses. The temperature-time curves were simulated by means of a new numerical calculation procedure. which took into account the temperature dependence of most physical data of water and the platinum wire. Temperature pulse voltammograms of cupric species were recorded. With 5 ms heat pulses a drastic increase in peak current and an improved signal-to-noise ratio was obtained. [References: 13]

机译：确定了热丝电化学中水过热的实验和理论极限。最高可达到的温度约为在5毫秒内250摄氏度听到脉冲。通过新的数值计算程序模拟了温度-时间曲线。考虑到水和铂丝的大多数物理数据对温度的依赖性。记录铜物种的温度脉冲伏安图。使用5 ms的热脉冲，峰值电流急剧增加，信噪比得到改善。 [参考：13]

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《Electroanalysis》 |2001年第9期|共5页
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Grundler P.; Degenring D.;
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正文语种 eng
中图分类电化学、电解、磁化学;
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1. The limits of aqueous hot-wire electrochemistry: Near-critical and supercritical fluids in electrochemical sensors? [J] . Grundler P., Degenring D. Electroanalysis . 2001,第8a9期

机译：水热丝电化学的局限性：电化学传感器中的近临界和超临界流体？
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4. Limits of Electrochemical Processes at Si Electrodes used at High Field for Aqueous Microfluidic MEMS Applications [C] . K. R. Zavadil, M. A. Rising, P. C. Galambos 202nd Meeting of the Electrochemical Society, May 12-17, 2002, Philadelphia, PA . 2002

机译：水磁场微流体MEMS应用中高场使用的Si电极的电化学过程限制
5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

机译：I.水溶液中汞电极上一氧化二氮和亚硝酸的电化学二。铁（III）和铁（II）的2,2'-联吡啶络合物的电化学和水解动力学；多种铁络合物的电化学动力学参数。三，铀（IV）-水溶液（氧化氘）中铀（IV）-乙撑双氨基乙酸复合物的质子核磁共振研究
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8. Electrochemistry in Near-Critical and Supercritical Fluids. 3. Studies of Br(-), I(-), and Hydroquinone in Aqueous Solutions [R] . Flarsheim, W. M., Tsou, Y. M., Trachtenberg, I., 1986

机译：近临界和超临界流体中的电化学。 3.水溶液中Br（ - ），I（ - ）和对苯二酚的研究

The limits of aqueous hot-wire electrochemistry: Near-critical and supercritical fluids in electrochemical sensors?

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