Applying immittance spectroscopy to monitoring hydrogen peroxide in the presence of ascorbic acid. Part I: Theoretical considerations

Iyengar S.; Hall EAH.

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Applying immittance spectroscopy to monitoring hydrogen peroxide in the presence of ascorbic acid. Part I: Theoretical considerations

机译：在抗坏血酸存在的情况下，应用电导光谱法监测过氧化氢。第一部分：理论上的考虑

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The theoretical prospect of utilizing AC immittance characterization of an electrochemical system to tailor the response for the selective amperometric monitoring of a kinetically less-favored analyte in the presence of a kinetically more-favored species is explored. The selective measurement of hydrogen peroxide in the presence of ascorbic acid is considered as a model case and an AC immittance model is developed from a first-principles approach based upon the partial differential equations governing transport and the kinetics of the electron transfers. The influence of various system parameters on the AC immittance spectra an investigated to identify the measurement conditions whereby the AC signal from hydrogen peroxide oxidation will be significantly larger than the AC signal from ascorbic acid. [References: 32]

机译：探索了利用电化学系统的交流阻抗表征来定制响应，以在存在动力学上更有利的物种时对动力学上较不利的分析物进行选择性安培监测的方法。在抗坏血酸存在下对过氧化氢的选择性测量被认为是一个模型案例，并且基于控制迁移和电子转移动力学的偏微分方程，从第一原理方法开发了一个交流电阻抗模型。为了确定测量条件，过氧化氢氧化的交流信号将明显大于抗坏血酸的交流信号，研究了各种系统参数对交流阻抗谱的影响。 [参考：32]

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《Electroanalysis》 |2001年第6期|共8页
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Iyengar S.; Hall EAH.;
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中图分类电化学、电解、磁化学;
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1. Applying immittance spectroscopy to monitoring hydrogen peroxide in the presence of ascorbic acid. Part I: Theoretical considerations [J] . Iyengar S., Hall EAH. Electroanalysis . 2001,第6期

机译：在抗坏血酸存在的情况下，应用电导光谱法监测过氧化氢。第一部分：理论上的考虑
2. Hydrogen peroxide generation in caco-2 cell culture medium by addition of phenolic compounds: effect of ascorbic acid. [J] . Roques SC, Landrault N, Teissedre PL, Free radical research . 2002,第5期

机译：通过添加酚类化合物在caco-2细胞培养基中产生过氧化氢：抗坏血酸的作用。
3. Erythrocyte defenses against hydrogen peroxide: the role of ascorbic acid. [J] . Mendiratta S, Qu Z, May JM Biochimica et biophysica acta: international journal of biochemistry and biophysics . 1998,第3期

机译：红细胞对过氧化氢的防御作用：抗坏血酸的作用。
4. THEORETICAL CONSIDERATIONS ON THE ROLES OF HYDROGEN BONDING IN THERMAL DECOMPOSITION OF PEROXIDES [C] . H ISOBE, S YAMANAKA, M OKUMURA, The 15th International Symposium on Bioluminescence and Chemilminescence(第十五届生物发光和化学发光国际会议)论文集 . 2008

机译：关于氢键在过氧化物热分解中作用的理论思考
5. Near infrared spectroscopy for monitoring bioreactor components and chemiluminescent sensors for hydrogen peroxide, glucose, and nitric oxide. [D] . Zhou, Xiangji. 1996

机译：近红外光谱仪用于监测生物反应器组件和化学发光传感器的过氧化氢，葡萄糖和一氧化氮。
6. Gas phase oxidants of cigarette smoke induce lipid peroxidation and changes in lipoprotein properties in human blood plasma. Protective effects of ascorbic acid. [O] . B Frei, T M Forte, B N Ames, 1991

机译：香烟烟雾中的气相氧化剂会引起人体血浆中脂质的过氧化和脂蛋白性质的变化。抗坏血酸的保护作用。
7. Decomposition of L-Ascorbic Acid in the Presence of D-Araboascorbic Acid. III. On Decomposition of L-Ascorbic Acid in the Presence of D-Araboascorbic Acid under Atmospheric Condition [O] . TOSHIO ANMO, MITSUNORI WASHITAKE, HIDEFUMI HAYASHI 1973

机译：在D-阿拉伯血红酸存在下L-抗坏血酸的分解。 III。大气条件下D-阿拉伯僵酸存在下L-抗坏血酸的分解
8. Hydrogen Peroxide-Induced Base Damage in Deoxyribonucleic Acid. [R] . Blakely, W. F., Fuciarelli, A. F., Weigher, B. J., 1990

机译：过氧化氢诱导的脱氧核糖核酸碱基损伤。

Applying immittance spectroscopy to monitoring hydrogen peroxide in the presence of ascorbic acid. Part I: Theoretical considerations

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