Electrochemical, in situ spectroelectrochemical, in situ electrocolorimetric and electrocatalytic characterization of metallophthalocyanines bearing four dioctylaminocarbonyl biphenyloxy substituents

Koca A.; Kalkan A.; Bayir Z.A.

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Electrochemical, in situ spectroelectrochemical, in situ electrocolorimetric and electrocatalytic characterization of metallophthalocyanines bearing four dioctylaminocarbonyl biphenyloxy substituents

机译：带有四个二辛基氨基羰基联苯氧基取代基的金属酞菁的电化学，原位光谱电化学，原位电比色和电催化表征

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This study describes the electrochemical, in situ spectroelectrochemical, in situ electrocolorimetric and electrocatalytic characterization of metallophthalocyanines bearing four dioctylaminocarbonyl biphenyloxy groups (MPc's). While CoPc gives both metal-based and ring-based redox processes, ZnPc and CuPc show only ring-based reduction and oxidation processes. In-situ electrocolorimetric method was applied to investigate color of the electrogenerated anionic and cationic forms of the complexes. Perchloric acid titrations monitored by cyclic voltammetry and spectrophotometry represent possible electrocatalytic activities of the complexes for hydrogen evolution reaction. CuPc having inactive metal center incorporated into a Nafion film on GCE decreases overpotential of the electrode for H~+ reduction in aqueous solution.

机译：这项研究描述了带有四个二辛基氨基羰基联苯氧基（MPc's）的金属酞菁的电化学，原位光谱电化学，原位电比色和电催化特性。虽然CoPc提供了金属基和环基氧化还原工艺，但ZnPc和CuPc仅显示了环基还原和氧化工艺。原位电比色法用于研究复合物电生成的阴离子和阳离子形式的颜色。通过循环伏安法和分光光度法监测的高氯酸滴定值表示该络合物对析氢反应的可能的电催化活性。在GCE上的Nafion膜中结合了非活性金属中心的CuPc降低了用于水溶液中H +还原的电极过电位。

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《Electroanalysis》 |2010年第3期|共10页
作者
Koca A.; Kalkan A.; Bayir Z.A.;
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正文语种 eng
中图分类电化学、电解、磁化学;
关键词
Chromaticity diagram; Cyclic voltammetry; Electrocatalyst; Hydrogen evolution reaction; Phthalocyanine; Spectroelectrochemistry;

机译：色度图循环伏安电催化剂氢气析出反应酞菁光谱电化学;

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1. Electrochemical, in situ spectroelectrochemical, in situ electrocolorimetric and electrocatalytic characterization of metallophthalocyanines bearing four dioctylaminocarbonyl biphenyloxy substituents [J] . Koca A., Kalkan A., Bayir Z.A. Electroanalysis . 2010,第3期

机译：带有四个二辛基氨基羰基联苯氧基取代基的金属酞菁的电化学，原位光谱电化学，原位电比色和电催化表征
2. Synthesis, electrochemical, in situ spectroelectrochemical and in situ electrocolorimetric characterization of new metal-free and metallophthalocyanines substituted with 4-{2-[2-(1-naphthyloxy)ethoxy]ethoxy} groups [J] . Acar I, Biyiklioglu Z, Koca A, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2010,第5期

机译：4- {2- [2-（2-（1-萘氧基）乙氧基]乙氧基}基团取代的新型无金属和金属酞菁的合成，电化学，原位光谱电化学和原位比色表征
3. Substituents effects to the electrochemical, and in situ spectroelectrochemical behavior of metallophthalocyanines: Electrocatalytic application for hydrogen evolution reaction [J] . Koca A., ?z?e?meci M., Hamuryudan E. Electroanalysis . 2010,第14期

机译：取代基对金属酞菁的电化学和原位光谱电化学行为的影响：析氢反应的电催化应用
4. Electrochemical and In situ Spectroelectrochemical Characterization of Single Microparticle Electrodes [C] . Attila Palencsar, Louis J.Rendek, Daniel A.Scherson The Meeting of the Electrochemical Society . 2002

机译：单微粒电极的电化学和原位光谱电化学特征
5. Electrochemical and spectroelectrochemical studies of tetraparadiethylaminophenylporphyrins, metalloporphyrins, metallophthalocyanines, micellar porphyrins and 4(a), 5-substituted flavins. [D] . Liu, Yaw-Hwa. 1988

机译：四对二乙基氨基苯基卟啉，金属卟啉，金属酞菁，胶束卟啉和4（a），5-取代的黄素的电化学和光谱电化学研究。
6. Spatially confined electrochemical conversion of metal–organic frameworks into metal-sulfides and their in situ electrocatalytic investigation via scanning electrochemical microscopy [O] . Itamar Liberman, Wenhui He, Ran Shimoni, 2020

机译：通过扫描电化学显微镜将金属有机骨架的空间局限于金属 - 有机骨架的电化学转化及其原位电催化研究
7. Capping polymer-enhanced electrocatalytic activity on Pt nanoparticles: a combined electrochemical and in situ IR spectroelectrochemical study [O] . Susut Ceren（Georgetown Univ Dept Chem）, Chen De-Jun, Sun Shi-Gang, 2011

机译：包覆聚合物增强的Pt纳米粒子的电催化活性：电化学和原位红外光谱电化学的联合研究
8. In situ and ex situ spectroelectrochemical and X-ray absorption studies on rechargeable, chemically-modified and other MnO(sub 2) materials. [R] . Conway, B. E., Qu, D., McBreen, J. 1992

机译：可再充电，化学改性和其他mnO（sub 2）材料的原位和非原位光谱电化学和X射线吸收研究。

Electrochemical, in situ spectroelectrochemical, in situ electrocolorimetric and electrocatalytic characterization of metallophthalocyanines bearing four dioctylaminocarbonyl biphenyloxy substituents

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