Multioperational oxidase biosensors based on carbosilane dendrimers with interacting ferrocenes

GarcíaMartínez M.; Alonso B.; Casado C.M.; Losada J.; García Armada M.P.

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Multioperational oxidase biosensors based on carbosilane dendrimers with interacting ferrocenes

机译：基于碳硅烷树枝状聚合物与相互作用的二茂铁的多操作氧化酶生物传感器

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The bioelectrocatalytical properties and kinetic characteristics of new oxidase biosensors based on two different carbosilane dendrimers are described. The best glucose biosensor developed displayed, in an ascorbate interference free work potential interval, a strictly linear range from 0 to 4.0mM, a detection limit of 40,6μM and a response time less than 3s. The lactate biosensor displayed a linear range from 0 to 0.8mM, a detection limit of 0.73μM and a response time less than 2s. The apparent Michaelis-Menten constants were calculated to be 4.39mM and 2.08mM respectively, according to Lineweaver-Burk equation.

机译：描述了基于两种不同碳硅烷树状聚合物的新型氧化酶生物传感器的生物电催化特性和动力学特性。研发出的最佳葡萄糖生物传感器在无干扰的工作电位区间内显示了从0到4.0mM的严格线性范围，40.6μM的检出限和不到3s的响应时间。乳酸生物传感器的线性范围为0至0.8mM，检测极限为0.73μM，响应时间小于2s。根据Lineweaver-Burk方程，表观Michaelis-Menten常数分别计算为4.39mM和2.08mM。

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《Electroanalysis》 |2011年第12期|共10页
作者
GarcíaMartínez M.; Alonso B.; Casado C.M.; Losada J.; García Armada M.P.;
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正文语种 eng
中图分类电化学、电解、磁化学;
关键词
Biosensors; Dendrimers; Enzyme catalysis; Glucose oxidase; Lactate oxidase;

机译：生物传感器;树枝状分子;酶催化;葡萄糖氧化酶;乳酸氧化酶;

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1. Multioperational oxidase biosensors based on carbosilane dendrimers with interacting ferrocenes [J] . GarcíaMartínez M., Alonso B., Casado C.M., Electroanalysis . 2011,第12期

机译：基于碳硅烷树枝状聚合物与相互作用的二茂铁的多操作氧化酶生物传感器
2. New Carbosilane Polymers with Interacting Ferrocenes as Support and Bioelectrocatalysts of Oxidases to Develop Versatile and Specific Amperometric Biodevices [J] . Garcia Armada M. Pilar, Jimenez Almudena, Losada Jose, Applied biochemistry and biotechnology, Part A. enzyme engineering and biotechnology . 2012,第7期

机译：具有交互作用的二茂铁作为载体和氧化酶的生物电催化剂的新型碳硅烷聚合物，可开发多功能和特定的安培生物装置
3. New Carbosilane Polymers with Interacting Ferrocenes as Support and Bioelectrocatalysts of Oxidases to Develop Versatile and Specific Amperometric Biodevices [J] . M. Pilar García Armada, Almudena Jiménez, José Losada, Applied biochemistry and biotechnology, Part A. enzyme engineering and biotechnology . 2012,第7期

机译：具有交互作用的二茂铁作为载体和氧化酶的生物电催化剂的新型碳硅烷聚合物，可开发多功能和特定的安培生物装置
4. Study on a pyruvate oxidase biosensor based on #x00DF;-cyclodextrin included ferrocene as electron-transfer mediator [C] . Tu Yifeng, Long Yumei, Deng Kejun International Conference on Sensing Technology . 2008

机译：基于β-环糊精的丙酮酸氧化酶生物传感器包括二茂铁作为电子转移介体的研究
5. Organometallic ferrocene-based polymers and poly(carbosilane)s prepared via transition-metal catalysis. [D] . Jain, Rajsapan. 2002

机译：通过过渡金属催化制备的基于有机金属二茂铁的聚合物和聚（碳硅烷）。
6. Multivalent Lactose–Ferrocene Conjugates Based on Poly (Amido Amine) Dendrimers and Gold Nanoparticles as Electrochemical Probes for Sensing Galectin-3 [O] . Manuel C. Martos-Maldonado, Indalecio Quesada-Soriano, Luis García-Fuentes, 2020

机译：基于聚（酰胺胺）树枝状大分子和金纳米粒子的多价乳糖-二茂铁结合物作为电化学探针检测Galectin-3。
7. Syntheses of Carbosilane Dendrimers Carrying Peripheral Globotriaose Derivatives-The Relationship between the Carbosilane Dendrimer Structure and the Magnitude for Neutralizing Shiga toxin-producing Escherichia coli O15 7:H7- [O] . Daiyo Terunuma, Koji Matsuoka, Ken Hatano 2005

机译：携带外周球蛋白衍生物的碳硅烷树枝状大分子的合成 - 碳硅烷树枝状大分子结构与中和毒素毒素的幅度之间的关系的关系与毒素产生的大肠杆菌O15 7：H7-
8. Liquid Crystalline Dendrimers: 2. Synthesis of Four Generations of Carbosilane LC Dendrimers with Terminal Methoxyphenylbenzoate Groups. Study of Phase Behaviour Structure and Mobility of mesogenic Groups of LC Dendrimers [R] . Shibaev, V. P. , Boiko, N. I. , Muzafarov, A. M. , 1998

机译：液晶树枝状大分子：2。具有末端甲氧基苯基苯甲酸酯基团的四代碳硅烷LC树枝状大分子的合成。 LC树枝状大分子的介晶基团的相行为结构和迁移率研究

Multioperational oxidase biosensors based on carbosilane dendrimers with interacting ferrocenes

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