A novel electrochemical method for the analysis of hydrogen peroxide with the use of a glassy carbon electrode modified by a prussian blue/copper-gold bimetallic nanoparticles hybrid film

Ni Y.; Song H.; Kokot S.

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A novel electrochemical method for the analysis of hydrogen peroxide with the use of a glassy carbon electrode modified by a prussian blue/copper-gold bimetallic nanoparticles hybrid film

机译：普鲁士蓝/铜金双金属纳米粒子杂化膜修饰的玻碳电极用于分析过氧化氢的新型电化学方法

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A novel Prussian blue/copper-gold bimetallic nanoparticles hybrid film modified electrode was prepared by electrochemical deposition on a glassy carbon electrode (PB/Cu-AuNPs/GCE). Morphology and electrochemistry of this electrode were studied by UV-vis spectroscopy, scanning electron microscopy, X-ray diffraction, cyclic voltammetry and electrochemical impedance spectroscopy. The sensor showed significantly better electrocatalytic activity for the reduction of hydrogen peroxide in comparison with the single PB/GCE and PB/AuNPs/GCE. This was attributed to the synergistic effect of PB and Cu-Au bimetallic nanoparticles. Also, the sensor demonstrated an overall high level of performance for the analysis of H2O2 in the concentration range from 0.002 to 0.84mM.

机译：通过在玻璃碳电极（PB / Cu-AuNPs / GCE）上进行电化学沉积，制备了一种新型的普鲁士蓝/铜-金双金属纳米颗粒杂化膜修饰电极。通过紫外可见光谱，扫描电子显微镜，X射线衍射，循环伏安法和电化学阻抗谱研究了该电极的形态和电化学。与单个PB / GCE和PB / AuNPs / GCE相比，该传感器在还原过氧化氢方面表现出明显更好的电催化活性。这归因于PB和Cu-Au双金属纳米颗粒的协同作用。而且，该传感器在浓度范围为0.002至0.84mM的H2O2分析中表现出总体上较高的性能。

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《Electroanalysis》 |2013年第9期|共10页
作者
Ni Y.; Song H.; Kokot S.;
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原文格式 PDF
正文语种 eng
中图分类 54.24;
关键词
Copper-gold bimetallic nanoparticles; Electrocatalysis; Hybrid film; Hydrogen peroxide; Prussian blue;

机译：铜金双金属纳米粒子;电催化;杂化膜;过氧化氢;普鲁士蓝;

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1. A novel electrochemical method for the analysis of hydrogen peroxide with the use of a glassy carbon electrode modified by a prussian blue/copper-gold bimetallic nanoparticles hybrid film [J] . Ni Y., Song H., Kokot S. Electroanalysis . 2013,第9期

机译：普鲁士蓝/铜金双金属纳米粒子杂化膜修饰的玻碳电极用于分析过氧化氢的新型电化学方法
2. Electrochemical determination of hydrogen peroxide using a novel prussian blue-polythiophene-graphene oxide membrane-modified glassy carbon electrode [J] . Liu Fang, An Baihong, Zhang Jingwei, Instrumentation science & technology: Designs and applications for chemistry, biotechnology, and environmental science . 2018,第2期

机译：一种新型普鲁士蓝 - 聚噻吩 - 石墨烯氧化物膜改性玻碳电极的电化学测定过氧化氢
3. Synthesis of Prussian Blue and Its Electrochemical Detection of Hydrogen Peroxide Based on Cetyltrimethylammonium Bromide (CTAB) Modified Glassy Carbon Electrode [J] . A. M. Farah, C. Billing, C. W. Dikio, International Journal of Electrochemical Science . 2013,第11期

机译：十六烷基三甲基溴化铵（CTAB）修饰玻碳电极的普鲁士蓝的合成及过氧化氢的电化学检测
4. Pt Nanoparticles-Assisted Electroless Deposition of Prussian Blue for Electrochemical Sensing of Hydrogen Peroxide with Tunable Sensitivity [C] . Jia ZHANG, Jing LI, Fan YANG, The Twelfth international symposium on electroanalytical chemistry : Program amp; extended abstracts . 2009

机译：Pt纳米粒子辅助化学镀普鲁士蓝，用于电化学感测具有可调灵敏度的过氧化氢
5. Electrochemical quartz crystal microbalance (EQCM) studies of films: Part 1. Ion and water transfers accompanying redox switching of Prussian Blue. Part 2. Adsorption of fibrinogen on gold modified electrodes with PPY. [D] . Kim, Ketack. 2002

机译：薄膜的电化学石英晶体微天平（EQCM）研究：第1部分。伴随普鲁士蓝的氧化还原转换而发生的离子和水转移。第2部分。纤维蛋白原在PPY修饰的金修饰电极上的吸附。
6. Electrochemical Sensor Based on Prussian Blue Electrochemically Deposited at ZrO2 Doped Carbon Nanotubes Glassy Carbon Modified Electrode [O] . Marlon Danny Jerez-Masaquiza, Lenys Fernández, Gema González, 2020

机译：基于普鲁士蓝的电化学传感器电化学沉积在ZrO2掺杂碳纳米管玻璃碳改性电极
7. Electrochemical determination of hydrogen peroxide at glassy carbon electrode modified with palladium nanoparticles [O] . Kitte Addisu Shimeles, Assresahegn Desalegn Birhanu, Soreta Refera Tesfaye 2013

机译：钯纳米粒子修饰玻碳电极上过氧化氢的电化学测定。

A novel electrochemical method for the analysis of hydrogen peroxide with the use of a glassy carbon electrode modified by a prussian blue/copper-gold bimetallic nanoparticles hybrid film

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