Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics

Prieto F.; Feldman M.; Coles BA.; Compton RG.; Oyama M. Okazaki S.; Alden JA.

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Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics

机译：用于机械电化学的通道微带电极阵列。二维伏安法：电极动力学

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The theory of "two-dimensional voltammetry" using arrays of gold channel microband electrodes ranging in size from the millimeter to the micrometer scale is extended to permit the deduction of electrochemical rate constants through the analysis of hydrodynamic voltammograms as a function of both electrode size and electrolyte flow rate (convection). The technique is applied to the reduction of p-chloranil and the oxidation of 2,3,7,8-tetramethoxythianthrene both in acetonitrile solution and electrochemical rate constants are reported. [References: 17]

机译：“二维伏安法”的理论得到了扩展，它使用了尺寸从毫米到微米尺度的金通道微带电极阵列，可以通过分析流体动力学伏安图作为电极尺寸和体积的函数来推导电化学速率常数。电解液流速（对流）。将该技术应用于对氯苯甲醛的还原反应，并报道了乙腈溶液中2,3,7,8-四甲氧基蒽的氧化和电化学速率常数。 [参考：17]

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《Electroanalysis》 |1999年第8期|共5页
作者
Prieto F.; Feldman M.; Coles BA.; Compton RG.; Oyama M. Okazaki S.; Alden JA.;
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正文语种 eng
中图分类电化学、电解、磁化学;
关键词
Two-dimensional voltammetry; Arrays of gold channel microband electrodes; P-chloranil; 2; 3; 7; 8-tetramethoxythianthrene; Electrochemical rate constants; Multigrid method; Simulation; Oxidation;

机译：二维伏安法;金通道微带电极阵列;对氯苯醌;2;3;7;8-四甲氧基噻吨;电化学速率常数;多重网格法;模拟;氧化;

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1. Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics [J] . Prieto F., Feldman M., Coles BA., Electroanalysis . 1999,第8期

机译：用于机械电化学的通道微带电极阵列。二维伏安法：电极动力学
2. Mechanistic Determination Using Arrays of Variable-Sized Channel Microband Electrodes: The Oxidation of Ascorbic Acid in Aqueous Solution [J] . Francisco Prieto, Barry A. Coles, Richard G. Compton The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 1998,第38期

机译：使用可变大小的通道微带电极阵列的机制测定：水溶液中抗坏血酸的氧化
3. Mechanistic Determination Using Arrays of Variable-Sized Channel Microband Electrodes: The Oxidation of Ascorbic Acid in Aqueous Solution [J] . Francisco Prieto, Barry A. Coles, Richard G. Compton The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 1998,第37a40期

机译：使用可变大小的通道微带电极阵列的机制测定：水溶液中抗坏血酸的氧化
4. Dielectrophoretic Patterning of Micropaticles Using a Three-Dimensional Microband-Array Electrode [C] . . 2005

机译：使用三维微带阵列电极对微颗粒进行介电泳图案化
5. DIRECT ELECTRON TRANSFER REACTIONS BETWEEN BIOLOGICAL REDOX MOLECULES AND CARBON FIBER ELECTRODES: MECHANISTIC AND KINETIC CONSIDERATIONS (ELECTROCHEMISTRY, CYTOCHROME C REDUCTASE, MICROVOLTAMMETRIC ELECTRODES) [D] . GERCHARIO, KIM ANN 1986

机译：生物氧化还原分子与碳纤维电极之间的直接电子转移反应：机理和动力学考虑（电化学，细胞色素C还原酶，微伏安电极）
6. Signal Amplification in a Microchannel from Redox Cycling with Varied Electroactive Configurations of an Individually-Addressable Microband Electrode Array [O] . Penny M. Lewis, Leah Bullard Sheridan, Robert E. Gawley, -1

机译：信号放大从氧化还原循环的微通道具有可单独寻址的微带阵列电极的电活性变配置
7. Theory and Experiments of Transport at Channel Microband Electrodes under Laminar Flows. 2. Electrochemical Regimes at Double Microband Assemblies under Steady State [O] . Amatore, Christian, Da Mota, Nicolas, Lemmer, Célia, 2008

机译：层流下通道微带电极传输的理论和实验。 2.稳态下双微带组件的电化学状态

Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics

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