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Applications of porous Pt-filled micropore electrode: Direct amperometric glucose detection and potentiometric pH sensing

机译:多孔Pt填充微孔电极的应用:直接安培葡萄糖检测和电位pH传感

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摘要

This paper reports the utilization of a micropore electrode as platform for the development of a nonenzymatic glucose microsensor. To facilitate direct glucose oxidation, a highly porous Pt (pPt) layer was deposited electrochemically on the Pt disk base in the pore. Compared to a pPt deposited planar Pt disk electrode, the higher sensitivity and selectivity of the pPt deposited micropore electrode could not only be attributed to the increased electrode roughness, but also to the small pore opening functioning as an efficient mass-transport resistance to the interfering species. The prepared pPt-micropore electrode also showed improved potentiometric responses to pH changes.
机译:本文报道了利用微孔电极作为开发非酶促葡萄糖微传感器的平台。为了促进葡萄糖的直接氧化,将高度多孔的Pt(pPt)层电化学沉积在孔中的Pt圆盘基体上。与pPt沉积的平面Pt圆盘电极相比,pPt沉积的微孔电极的较高灵敏度和选择性不仅可以归因于电极粗糙度的增加,而且还可以归因于小孔的开放,从而有效地抵抗了干扰种类。制备的pPt-微孔电极还显示出对pH变化的改进的电位响应。

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