A DEMS Study of the Reduction of CO2, CO, and HCHO Pre-Adsorbed on Cu Electrodes: Empirical Inferences on the CO2RR Mechanism

Javier Alnald; Chmielowiec Brian; Sanabria-Chinchilla Jean; Kim Youn-Geun; Baricuatro Jack H.; Soriaga Manuel P.

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A DEMS Study of the Reduction of CO2, CO, and HCHO Pre-Adsorbed on Cu Electrodes: Empirical Inferences on the CO2RR Mechanism

机译：预先吸附在铜电极上的CO2，CO和HCHO还原的DEMS研究：对CO2RR机理的经验推论

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《Electrocatalysis》 |2015年第2期|共5页
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Javier Alnald; Chmielowiec Brian; Sanabria-Chinchilla Jean; Kim Youn-Geun; Baricuatro Jack H.; Soriaga Manuel P.;
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正文语种 eng
中图分类化学动力学、催化作用;
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1. A DEMS Study of the Reduction of CO2, CO, and HCHO Pre-Adsorbed on Cu Electrodes: Empirical Inferences on the CO2RR Mechanism [J] . Javier Alnald, Chmielowiec Brian, Sanabria-Chinchilla Jean, Electrocatalysis . 2015,第2期

机译：预先吸附在铜电极上的CO2，CO和HCHO还原的DEMS研究：对CO2RR机理的经验推论
2. Mechanistic Understanding of CO2 Reduction Reaction (CO2RR) Toward Multicarbon Products by Heterogeneous Copper-Based Catalysts [J] . Todorova Tanya K., Schreiber Moritz W., Fontecave Marc ACS catalysis . 2020,第3期

机译：通过异质铜基催化剂对二氧化碳产品（CO2RR）对多元铜产物的机械理解理解
3. Reaction Mechanism of Cu(I)-Mediated Reductive CO2 Coupling for the Selective Formation of Oxalate: Cooperative CO2 Reduction To Give Mixed-Valence C(u)2(CO2 center dot-) and Nucleophilic-Like Attack [J] . Lan Jialing, Liao Tao, Zhang Tonghuan, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2017,第12期

机译：Cu（I）介导的Reductive CO2偶联的反应机理，用于选择性形成草酸盐：合作二氧化碳还原，得到混合价C（U）2（CO2中心点 - ）和亲核状攻击
4. Electrocatalytic Reduction of CO_2 on Cu and Au/W Electrode Surfaces: Empirical (DEMS) Confirmation of Computational (DFT) Predictions [C] . A. Javier, J. H. Baricuatro, Y. G. Kim, Meeting of the Electrochemical Society . 2017

机译：Cu和Au / W电极表面上CO_2的电催化还原：经验（DEMS）确认计算（DFT）预测
5. Mechanism of acid reduction at low and high overpotential metal electrodes in the presence and absence of CO2: Implications for CO2 reduction by N-heterocycles. [D] . Zeitler, Elizabeth L. 2014

机译：在存在和不存在CO2的情况下，低电位和高电位金属电极上酸还原的机理：N杂环对CO2还原的影响。
6. Subsurface oxide plays a critical role in CO2 activation by Cu(111) surfaces to form chemisorbed CO2 the first step in reduction of CO2 [O] . Marco Favaro, Hai Xiao, Tao Cheng, 2017

机译：地下氧化物在通过Cu（111）表面活化CO2以形成化学吸附的CO2中起关键作用这是减少CO2的第一步
7. Surface-reconstructed Cu electrode via a facile electrochemical anodization-reduction process for low overpotential CO2 reduction [O] . Shixiong Min, Xiulin Yang, Ang-Yu Lu, 2017

机译：表面重建的Cu电极通过简便的电化学阳极氧化还原工艺实现低过电位CO2还原
8. Mechanisms of CO2 Reduction on Metal and Modified Semiconductor Electrodes [R] . Frese, K. W., Summers, D. P. 1986

机译：二氧化碳还原金属和改性半导体电极的机制

A DEMS Study of the Reduction of CO2, CO, and HCHO Pre-Adsorbed on Cu Electrodes: Empirical Inferences on the CO2RR Mechanism

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