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首页> 外文期刊>Electrocatalysis >Electrocatalytic Dechlorination of Atrazine Using Binuclear Iron Phthalocyanine as Electrocatalysts
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Electrocatalytic Dechlorination of Atrazine Using Binuclear Iron Phthalocyanine as Electrocatalysts

机译：双核酞菁铁为电催化剂对At去津的电催化脱氯

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摘要

The electrochemical reduction approach has been suggested as a promising method for detoxification of chlorine-containing aromatic hydrocarbons. In this study, the electrocatalytic dechlorination of atrazine was studied by using a non-noble catalyst, binuclear iron phthalocyanine coated onto multi-walled carbon nanotubes (bi-FePc/MWNT). Both experimental and theoretical results indicate that dechlorination of atrazine occurs rapidly on bi-FePc/MWNT electrode. The reaction depends on the adsorption of the chlorinated organic compound on the electrode surface and the reaction rate with hydroxy. By liquid chromatography-tandem mass spectrometer technique, the dechlorination product of atrazine can be assigned to 2-hydroxy-4-ethylamino-6-isopropylamino-1,3,5-triazine, which could be disposed by more convenient and economic biodegradation method.
机译：已经提出了电化学还原方法作为用于含氯芳烃的解毒的有前途的方法。在这项研究中，对using去津的电催化脱氯进行了研究，方法是使用非贵金属催化剂双核酞菁铁涂覆在多壁碳纳米管上（bi-FePc / MWNT）。实验和理论结果均表明at去津的脱氯作用在bi-FePc / MWNT电极上迅速发生。反应取决于电极表面上氯化有机化合物的吸附以及与羟基的反应速率。通过液相色谱-串联质谱技术，可以将阿特拉津的脱氯产物分配给2-羟基-4-乙基氨基-6-异丙氨基-1,3,5-三嗪，可以通过更方便，更经济的生物降解方法对其进行处理。

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