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Enhanced electron transfer properties of carbon spheres chains via electrochemical functionalization

机译:通过电化学功能化增强碳球链的电子转移性能

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摘要

Electrochemical functionalization via electrochemical oxidation in nitric acid of various concentrations (0.1M, 0.2M and 2M) was employed to enrich the surface of carbon sphere chains (CSCs) with some useful physico-chemical properties such as hydrophilicity, oxygen functionalities and electron transfer properties. The functionalization process in 2M HNO_3 solution led to the creation of an original hybrid material made of carbon sphere chains-carbon nanobuds. This material displayed a prominent response towards the electrocatalytic oxidation of ferrocyanide with a peak current three times and twice superior to those delivered by pristine CSC and multiwalled carbon nanotubes (MWCNTs) electrodes, respectively.
机译:通过在各种浓度(0.1M,0.2M和2M)的硝酸中通过电化学氧化进行电化学功能化,以使碳球链(CSC)的表面富集一些有用的理化性质,例如亲水性,氧官能度和电子转移性质。在2M HNO_3解决方案中的功能化过程导致了由碳球链-碳纳米芽制成的原始混合材料的创建。该材料显示出对亚铁氰化物的电催化氧化的显着响应,其峰值电流分别比原始CSC和多壁碳纳米管(MWCNT)电极传递的峰值电流分别高三倍和两倍。

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