On the kinetics of the nitrate reduction in concentrated nitric acid

Lange R.; Maisonhaute E.; Robin R.; Vivier V.

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On the kinetics of the nitrate reduction in concentrated nitric acid

机译：浓硝酸中硝酸盐还原的动力学

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The autocatalytic mechanism involved in the reduction reaction of nitrate in 8 M nitric acid solution was investigated in order to propose a complete description of all processes taking place at the interface. A time and potential independent current plateau was observed for low scan rates and was ascribed to limitation by the desorption of NO_(ads). Data analysis and fit of the experimental chronoamperogram allowed determination of the kinetic constants of the autocatalytic cycle.

机译：研究了在8 M硝酸溶液中硝酸盐还原反应中涉及的自催化机理，以便全面描述在界面处发生的所有过程。对于低扫描速率，观察到了时间和电位独立的电流平稳期，并归因于NO_（ads）的解吸。数据分析和实验计时电流图的拟合使得可以确定自催化循环的动力学常数。

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《Electrochemistry communications》 |2013年第null期|共4页
作者
Lange R.; Maisonhaute E.; Robin R.; Vivier V.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Autocatalysis; Chronoamperometry; Nitrate reduction; Nitric acid;

机译：自催化;计时安培法;硝酸盐还原;硝酸;

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1. On the kinetics of the nitrate reduction in concentrated nitric acid [J] . Lange R., Maisonhaute E., Robin R., Electrochemistry communications . 2013,第Null期

机译：浓硝酸中硝酸盐还原的动力学
2. Decay Mechanism of NO3 center dot Radical in Highly Concentrated Nitrate and Nitric Acidic Solutions in the Absence and Presence of Hydrazine [J] . Garaix Guillaume, Horne Gregory P., Venault Laurent, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2016,第22期

机译：在有和没有肼存在下高浓度硝酸盐和硝酸溶液中NO3中心点自由基的衰减机理
3. Nitration of phenols in reversed micelle systems and enhanced oxidation ability of dilute nitric acid (less than 2.0 molarity) in concentrated salt solutions [J] . Hojo M., Kato R., Narutaki A., Journal of Molecular Liquids . 2011,第3期

机译：反向胶束系统中酚的硝化和浓盐溶液中稀硝酸（小于2.0摩尔浓度）的氧化能力增强
4. THE NITRATION KINETIC OF 6-HYDROXY-2-METHYLPYRIMIDINE-4(3H)-ONE IN SULFURIC-NITRIC ACID MIXTURES [C] . A.A.Kushtaev, A.V.Djakonov, N.V.Yudin, Seminar of the New Trends in Research of Energetic Materials;NTREM '08 . 2008

机译：硫酸-硝酸混合物中6-羟基-2-甲基嘧啶-4（3H）-1的硝化动力学
5. Observations of nitrites, peroxy nitrates, alkyl nitrates, nitric acid , and total nitrogen oxides in Houston, Texas: Implications for ozone photochemistry. [D] . Rosen, Rebecca Sarah. 2004

机译：在德克萨斯州休斯顿的亚硝酸盐，过氧硝酸盐，硝酸烷基酯，硝酸和总氮氧化物的观测：对臭氧光化学的影响。
6. Nitric Oxide Production by the Human Intestinal Microbiota by Dissimilatory Nitrate Reduction to Ammonium [O] . Joan Vermeiren, Tom Van de Wiele, Willy Verstraete, 2009

机译：通过异化硝酸盐还原为铵盐人体肠道菌群产生一氧化氮。
7. On the kinetics of the nitrate reduction in concentrated nitric acid [O] . Lange, Ronny, Maisonhaute, Emmanuel, Robin, Raphaël, 2013

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8. A STUDY OF THE OXIDATION-REDUCTION KINETICS INVOLVED IN THE Np(Ⅴ) + Fe(Ⅱ) = Np(Ⅳ) + Fe(Ⅲ) SYSTEM IN NITRIC ACID SOLUTIONS [R] . Yun Jao 1975

机译：Np（Ⅴ）+ Fe（Ⅱ）= Np（Ⅳ）+ Fe（Ⅲ）体系在硝酸溶液中氧化还原动力学的研究

On the kinetics of the nitrate reduction in concentrated nitric acid

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