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Crystal growth mechanisms in inorganic glasses

机译:无机玻璃中的晶体生长机理

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摘要

There exist three standard phenomenological models (normal growth,screw dislocation growth and 2-D nucleated gowth) that have been employed for the description of interface crystal growth processes in inorganic glasses.it was believed that one could decide which of these growth models was operative in a given system by inspectionof a plot of the reduced growth rate,U_R,as a function of undercooling.#DELTA#T.However,we have discovered that discerning the mechaism entails a more complex analysis,for which one has to compare the magnitudes of experiemntal and calculated growth rates as well as assess the physical parameters that ente rinto the theories.Furthermore,we have observed that growth mechanisms can change (perhaps several times) as the degree of undercooling of the melt is increased.We illustrate these points by means of analysing,and in some cases reanalysing,crystal growth data obtained for several different inorganic glasses.Since we limit our attention to interface controlled processes,only pseudo one component glasses where thermal dissipation effects are neglibible are considered.
机译:现有三种标准的现象学模型(正常生长,螺钉位错生长和二维有核Gowth)用于描述无机玻璃中界面晶体的生长过程。据信,一个模型可以决定哪种生长模型是有效的。在给定系统中,通过检查降低的增长率U_R与过冷度的函数关系图。#DELTA#T。但是,我们已经发现,辨别机械机理需要进行更复杂的分析,为此必须对幅度进行比较我们还观察到,随着熔体过冷度的增加,生长机理可能会发生变化(也许是几次)。几种不同无机玻璃的晶体生长数据的分析手段,在某些情况下还会重新分析。由于我们将注意力集中在界面控制上在此过程中,仅考虑散热效果可忽略的假一组分玻璃。

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