首页> 外文期刊>European Journal of Glass Science and Technology, PartB. Physics and Chemistry of Glasses >Structure and chemical studies of As_2S_3 glasses used for waveguide applications
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Structure and chemical studies of As_2S_3 glasses used for waveguide applications

机译:波导应用As_2S_3玻璃的结构与化学研究

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摘要

Chalcogenide glasses based on As_2S_3 have been studied extensively due to their optical and electronic properties and have been examined recently for use in optical waveguide components. Structural and chemical variations imposed by processing conditions (film deposition or fibre drawing) can lead to changes in linear and nonlinear optical properties as well as other physical properties. This paper reports our current results on x-ray photoelectron spectroscopy (XPS) studies of the resulting chemical composition at the film surface as compared to the parent bulk glass and the corresponding variation in the nature of chemical bonds and electronic structure. Special emphasis is focused on identification of bridging versus nonbridging sulphur atoms using XPS chemical shifts. Variations, where present, in surface chemistry due tot eh effect of x-ray exposure, sputtering and laser irradiation on bulk and thin film As_2S_3 samples are reported.
机译:基于As_2S_3的硫属化物玻璃由于其光学和电子特性而得到了广泛的研究,并且最近已被研究用于光波导部件中。加工条件(膜沉积或纤维拉伸)带来的结构和化学变化会导致线性和非线性光学性质以及其他物理性质发生变化。本文报告了我们当前在X射线光电子能谱(XPS)研究中与母体玻璃相比在薄膜表面产生的化学成分以及化学键和电子结构的性质相应变化的结果。特别强调的是使用XPS化学位移识别桥连和非桥连的硫原子。据报道,由于X射线曝光,溅射和激光辐照对大块和薄膜As_2S_3样品的影响,在表面化学中存在变化。

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