Self-Assembly of Protonated 1,12-Dodecanediamine Molecules and Strongly Undulated Uranyl Selenate Sheets in the Structure of Amine-Templated Uranyl Selenate:(H_3O)_2[C_(12)H_3ON_2]_3[(UO_2)_4(SeO_4)_8](H_2O)_5

Sergey V.Krivovichev; Evgeniya Yu.Avdontseva; Edgar Mersdorf; Reinhard Kaindl; Volker Kahlenberg

首页> 外文期刊>European journal of inorganic chemistry >Self-Assembly of Protonated 1,12-Dodecanediamine Molecules and Strongly Undulated Uranyl Selenate Sheets in the Structure of Amine-Templated Uranyl Selenate:(H_3O)_2[C_(12)H_3ON_2]_3[(UO_2)_4(SeO_4)_8](H_2O)_5

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Self-Assembly of Protonated 1,12-Dodecanediamine Molecules and Strongly Undulated Uranyl Selenate Sheets in the Structure of Amine-Templated Uranyl Selenate:(H_3O)_2[C_(12)H_3ON_2]_3[(UO_2)_4(SeO_4)_8](H_2O)_5

机译：胺模板化铀酰硒酸酯结构中的质子化1,12-十二烷二胺分子和强起伏的铀酰硒酸酯片的自组装：（H_3O）_2 [C_（12）H_3ON_2] _3 [（UO_2）_4（SeO_4）_8]（ H_2O）_5

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The amine-templated uranyl selenate (H_3O)_2[C_(12)H_3ON_2]_3-[(UO_2)_4(SeO_4)_8](H_2O)_5 (1) has been prepared.Its structure [monoclinic,P2_1,a=11.3437(7),b=24.8042(12),c=29.2496(19) A,beta=96.701(5)deg,V=8173.8(8) A~3,Z=4,R_1=0.083] is based upon strongly undulating [(UO_2)(SeO_4)_2]~(2-) sheets consisting of corner-sharing UO_7 bipyramids and SeO_4~(2-) tetrahedra.The undulations of the adjacent sheets have an anti-phase character that allows the formation of large eliptical channels that are occupied by rod micelles formed by self-assembly of protonated 1,12-dodecanedi-amine molecules.

机译：制备了胺模板的硒酸铀酸酯（H_3O）_2 [C_（12）H_3ON_2] _3-[（UO_2）_4（SeO_4）_8]（H_2O）_5（1）。其结构为[单斜晶系，P2_1 / n，a = 11.3437（7），b = 24.8042（12），c = 29.2496（19）A，beta = 96.701（5）deg，V = 8173.8（8）A〜3，Z = 4，R_1 = 0.083]基于强起伏的[（UO_2）（SeO_4）_2]〜（2-）片，由角共享的UO_7双锥和SeO_4〜（2-）四面体组成。相邻片的起伏具有反相特性，可形成较大的椭圆形通道被质子化的1,12-十二烷二胺分子自组装形成的杆状胶束占据。

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《European journal of inorganic chemistry》 |2005年第9期|共4页
作者
Sergey V.Krivovichev; Evgeniya Yu.Avdontseva; Edgar Mersdorf; Reinhard Kaindl; Volker Kahlenberg;
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正文语种 eng
中图分类无机化学;
关键词
Host-guest systems; Layered compounds; Selenium; Self-assembly; Uranium;

机译：客座系统;分层化合物;硒;自组装;铀;

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1. Self-Assembly of Protonated 1,12-Dodecanediamine Molecules and Strongly Undulated Uranyl Selenate Sheets in the Structure of Amine-Templated Uranyl Selenate:(H_3O)_2[C_(12)H_3ON_2]_3[(UO_2)_4(SeO_4)_8](H_2O)_5 [J] . Sergey V.Krivovichev, Evgeniya Yu.Avdontseva, Edgar Mersdorf, European journal of inorganic chemistry . 2005,第9期

机译：胺模板化铀酰硒酸酯结构中的质子化1,12-十二烷二胺分子和强起伏的铀酰硒酸酯片的自组装：（H_3O）_2 [C_（12）H_3ON_2] _3 [（UO_2）_4（SeO_4）_8]（ H_2O）_5
2. Synthesis and Crystal Structure of the First Uranyl Selenite(IV)-Selenate(VI)[C_5H_(14)N][(UO_2)(SeO_4)(SeO_2OH)] [J] . S.V.Krivovichev, I.G.Tananaev, V.Kahlenberg Doklady Physical Chemistry . 2005,第0期

机译：第一铀酰硒沸石（IV）的合成和晶体结构 - 硒酸酯（VI）[C_5H_（14）N] [（UO_2）（SEO_4）（SEO_2OH）]
3. Amine-templated uranyl selenates with layered structures. I - Structural diversity of sheets with a U : Se ratio of 1 : 2 [J] . Krivovichev SV, Kahlenberg V, Tananaev IG, Zeitschrift fur Anorganische und Allgemeine Chemie . 2005,第12期

机译：胺模板的铀酰亚硒酸酯具有层状结构。 I-U：Se比为1：2的板材的结构多样性

Self-Assembly of Protonated 1,12-Dodecanediamine Molecules and Strongly Undulated Uranyl Selenate Sheets in the Structure of Amine-Templated Uranyl Selenate:(H_3O)_2[C_(12)H_3ON_2]_3[(UO_2)_4(SeO_4)_8](H_2O)_5

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