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Computational Studies on the Sulfur Dioxide Absorption by Organic Lewis Bases

机译:有机路易斯碱吸收二氧化硫的计算研究

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摘要

The flue gas emitted by burning of fossil fuels is a significant source of the atmospheric sulfur dioxide (SO2). As SO2 can produce eventually sulfuric acid after oxidation and reaction with water, it is considered as one of the main sources causing acid rain. To prevent the environmentally harmful gas from exposing to atmosphere, the flue gas de-sulfurization (FGD) processes such as limestone-scrubbing and chemical absorption are requested in the fire power plant. Currently, among many sorbents limestone (CaCO3) is widely used for a scrubbing process which utilizes the chemical reaction between CaCO3 and SO2 to give solid CaSO3. As this process gives a large amount of solid waste cakes as by-products as well, the new absorption methods using organic solvents as SO2-removal agents have been explored because the absorbing agents can be regenerated repeatedly.
机译:化石燃料燃烧所产生的烟气是大气中二氧化硫(SO2)的重要来源。由于SO2在氧化并与水反应后最终会产生硫酸,因此被认为是引起酸雨的主要来源之一。为了防止对环境有害的气体暴露于大气中,在火力发电厂中要求进行烟气脱硫(FGD)工艺,例如石灰石洗涤和化学吸收。当前,在许多吸附剂中,石灰石(CaCO 3)被广泛用于洗涤过程,该过程利用CaCO 3和SO 2之间的化学反应产生固体CaSO 3。由于该方法也产生大量的副产品固体废饼,因此已探索了使用有机溶剂作为SO2去除剂的新吸收方法,因为吸收剂可以重复再生。

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