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Novel Linking Ligand Containing Sulfur-Donor Atoms and Its Compounds of Palladium and Silver

机译:新型含硫给体原子的连接配体及其钯和银化合物

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摘要

A linking ligand containing sulfur donor atoms in the terminal thiophene rings,l,2-bis(thiophen-2-ylmeth-ylene)hydrazine (L),was prepared by Schiff-base condensation.Ligand L reacted with [PdCl2(NCPh)2] to produce a molecular Pd compound [PdL2Cl2] (1).On the other hand,it reacted with AgNO3 and AgClO4 to produce a 2-D network [AgL0.5(NO3)] (2) and a 1-D polymer [AgL]ClO4 (3),respectively,whose structures are based on secondary intermolecular forces such as H-bonding,van der Waals interaction,and pi-pi stacking.Polymer 2 exhibited photoluminescence at room temperature in the solid state.
机译:通过席夫碱缩合制备末端噻吩环中含硫供体原子的连接配体l,2-双(噻吩-2-基亚甲基)肼(L)。配体L与[PdCl2(NCPh)2]反应]生成分子Pd化合物[PdL2Cl2](1)。另一方面,它与AgNO3和AgClO4反应生成2-D网络[AgL0.5(NO3)](2)和1-D聚合物[ AgL] ClO4(3)的结构分别基于次级分子间作用力,例如H键,范德华相互作用和pi-pi堆积。聚合物2在室温下呈固态发光。

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