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Volumetric Nucleation of Crystals Catalyzed by Cr2O3 in Glass Based on Furnace Slags

机译:基于炉渣的玻璃中Cr2O3催化晶体的体积成核

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摘要

The features of the volumetric nucleation of crystals in glass obtained by melting furnace slags with the additive of SiO2, chromium sesquioxide Cr2O3, are studied by the methods of differential thermal and X-ray phase analysis and optical microscopy. Upon the introduction of Cr2O3 as the catalytic additive, two phases are sequentially formed in the glass: magnesiochromite (MgO center dot Cr2O3) and diopside (CaO center dot MgO center dot 2SiO(2)). The characteristics of homogeneous and heterogeneous crystallization are determined: the stationary nucleation rate, nonstationary nucleation time, crystal growth rate, and their temperature dependences are obtained. Practical recommendations on the use of the obtained glass are given.
机译:采用差热分析和X射线相分析及光学显微镜的方法研究了熔渣与SiO2,三氧化二铬Cr2O3的熔融过程中玻璃熔体晶体的形核特征。在引入Cr2O3作为催化添加剂后,玻璃中依次形成了两相:镁铬铁矿(MgO中心点Cr2O3)和透辉石(CaO中心点MgO中心点2SiO(2))。确定了均相和非均相结晶的特征:获得了固定成核速率,非平稳成核时间,晶体生长速率及其温度依赖性。给出了使用所得玻璃的实用建议。

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