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首页> 外文期刊>Fibers and Polymers >Synthesis and Application of Novel High Light Fastness Red Dyes for Ultra High Molecular Weight Polyethylene Fibers
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Synthesis and Application of Novel High Light Fastness Red Dyes for Ultra High Molecular Weight Polyethylene Fibers

机译:超高分子量聚乙烯纤维用新型高耐晒红染料的合成与应用

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摘要

A new series of anthraquinoid red dyes were synthesized with l-amino-2-bromo-4-hydroxyanthraquinone and n-alkylphenols to dye UHMWPE fibers with high light fastness. Their dyeability was examined depending on the length of alkyl chains. As the length of alkyl substituents increases, the dyeability toward UHMWPE fibers improves rapidly from methyl to ethyl substituents and maintains almost same level of color strength, and then decreases from heptyl to octyl groups. The color strength of dyeings increased dramatically with the increase of dyeing temperature from 100 °C to 130 °C. The maximum build-up was shown at around 5 % owf dye amount. From the dyeing rate, equilibrium dyeing was achieved at around 5 h at 130 °C. All kinds of fastnesses were good enough showing higher than ratings 4-5 to washing and rubbing for the longer alkyl substituents. Especially, much improvement was achieved in light fastness showing ratings 4, which was higher than ratings 2 of the previous study.
机译:用1-氨基-2-溴-4-羟基蒽醌和正烷基苯酚合成了一系列新的蒽醌类红色染料,以高耐晒度染色UHMWPE纤维。根据烷基链的长度检查其可染性。随着烷基取代基长度的增加,对UHMWPE纤维的染色性从甲基取代基迅速提高到乙基取代基,并保持几乎相同水平的色强度,然后从庚基降低到辛基。染色的色强度随着染色温度从100°C到130°C的增加而急剧增加。最大堆积量显示在owf染料量的5%左右。从染色速度来看,在130°C下约5小时即可达到平衡染色。各种牢度都足够好,对于较长的烷基取代基,其洗涤和摩擦性能高于等级4-5。尤其是,显示4级的耐光性大大提高,高于先前研究的2级。

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