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Patterns of solid-fluid phase equilibria II. Interplay with fluid phase criticality and stability

机译:固液相平衡模式II。与液相关键性和稳定性相互作用

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In an earlier paper, the van der Waals equation of state was used in combination with a common mathematical artifice for the solid-phase fugacity function to map out the sig loci for a model binary homologous series of solvent + solute mixtures as a function of the solute's parametric characterization. The computations suggested new possibilities for solid-fluid phase equilibrium topography, heretofore not reported in the literature. To provide a better understanding of these computations, the authors have computed and mapped out the critical point loci, concurrently applying phase and system stability analysis. These new computations, which confirm the earlier solid-fluid computations, provide a detailed picture of how the solid-fluid topography for this particular series of model mixtures evolves as solvent-solute parametric differences increase. (C) 2000 Elsevier Science B.V. All rights reserved. [References: 13]
机译:在较早的论文中,将范德华状态方程与固相逸度函数的通用数学方法结合使用,以绘制溶剂+溶质混合物的模型二元同源序列的信号轨迹作为函数的函数。溶质的参数表征。该计算为固-液相平衡形貌提出了新的可能性,迄今为止尚未在文献中报道。为了更好地理解这些计算,作者已经计算并绘制了临界点位置,同时应用了相位和系统稳定性分析。这些新的计算结果证实了较早的固相流体计算结果,提供了有关此特定系列模型混合物的固相流体形貌如何随着溶剂-溶质参数差的增加而变化的详细图片。 (C)2000 Elsevier Science B.V.保留所有权利。 [参考:13]

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