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首页> 外文期刊>Fluid Phase Equilibria >Comparison of different methods for determination of the S-L-G equilibrium curve of a solid component in the presence of a compressed gas
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Comparison of different methods for determination of the S-L-G equilibrium curve of a solid component in the presence of a compressed gas

机译：在压缩气体存在下测定固体组分S-L-G平衡曲线的不同方法的比较

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摘要

Two different experimental techniques for determination of the solid-liquid-gas (S-L-G) phase equilibria in systems with a compressed gas are presented and compared: the modified capillary method and the modified freezing method. The phase behavior of the binary systems (napthalene/CO2, biphenyl/CO2, vanillin/CO2, ethyl-o-vanillin/CO2, low-density polyethylene/CO2 and benzoic acid/CO2) were determined experimentally with both methods. The S-L-G lines for all systems shows a temperature minimum in the p-T projection. The difference in melting temperature between the two experimental methods was +/- 0.4 K. (C) 2000 Elsevier Science B.V. All rights reserved. [References: 16]
机译：提出并比较了两种不同的测定压缩气体系统中固液气（S-L-G）相平衡的实验技术：改进的毛细管法和改进的冷冻法。用两种方法实验确定了二元体系（萘/ CO2，联苯/ CO2，香草醛/ CO2，乙基邻香兰素/ CO2，低密度聚乙烯/ CO2和苯甲酸/ CO2）的相行为。所有系统的S-L-G线均在p-T投影中显示出最低温度。两种实验方法之间的熔融温度差为+/- 0.4K。（C）2000 Elsevier Science B.V.保留所有权利。 [参考：16]

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