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首页> 外文期刊>Fluid Phase Equilibria >Modeling the thermodynamic and transport properties of decahydronaphthalene/propane mixtures: Phase equilibria, density, and viscosity
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Modeling the thermodynamic and transport properties of decahydronaphthalene/propane mixtures: Phase equilibria, density, and viscosity

机译:模拟十氢萘/丙烷混合物的热力学和传输性质:相平衡,密度和粘度

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摘要

The density and viscosity of propane mixed with 66/34 trans/cis-decahydronaphthalene were measured over a wide range of temperatures (323-423. K), pressures (2.5-208. bar), and compositions (0-65. mol% propane). For conditions giving two phases, the composition of the dense phase was measured in addition to the density and viscosity. The modified Sanchez-Lacombe Equation of State (MSLEOS) was used with a single linearly temperature-dependent pseudo-binary interaction parameter to correlate the phase compositions and densities. The compositions and densities of the mixtures were captured well with absolute average deviations between the model and the data of 5.3% and 2.3%, respectively. The mixture viscosities were computed from a free volume model (FVM) by using a single constant binary interaction parameter. Density predictions from the MSLEOS were used as input mixture density values required for the FVM. The FVM was found to correlate well with the mixture viscosity data with an absolute average deviation between the model and the data of 5.7%.
机译:在很宽的温度范围(323-423。K),压力范围(2.5-208。bar)和组成范围(0-65。mol%)下测量了与66/34反式/顺式-十氢萘混合的丙烷的密度和粘度丙烷)。对于给出两相的条件,除了密度和粘度之外,还测量了致密相的组成。修改后的Sanchez-Lacombe状态方程(MSLEOS)与单个线性依赖温度的伪二元相互作用参数一起使用,以关联相组成和密度。很好地捕获了混合物的组成和密度,模型和数据之间的绝对平均偏差分别为5.3%和2.3%。通过使用单个常数二元相互作用参数从自由体积模型(FVM)计算混合物粘度。来自MSLEOS的密度预测用作FVM所需的输入混合物密度值。发现FVM与混合物粘度数据具有很好的相关性,模型与数据之间的绝对平均偏差为5.7%。

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