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Gas storage in fullerenes

机译:富勒烯中的气体储存

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Fullerenes and in particular C_(60) have been shown to store effectively a wide range of gases from simple monatomic rare gases to diatomics and polyatomics. A review of the research in this area conducted at ANSTO is given. The trapping of Ar, Kr, Xe, and CO_2 are discussed in detail whilst preliminary results pertaining to N_2O, CH_4, CF_4, C_2H_6 and SF_6 are also reported. A range of techniques have been used to elucidate both the structure of the new fullerene intercalated solid and the trapped gas itself. The preponderant techniques used, include infra-red absorption spectroscopy (IR), X-ray powder diffraction a (XRD), neutron powder diffraction (NRD), transmission electron microscopy (TEM), and thermal gravimetric analysis (TGA).
机译:富勒烯,尤其是C_(60)已被证明可以有效地存储从简单的单原子稀有气体到双原子和多原子的各种气体。本文对ANSTO在这一领域的研究进行了综述。详细讨论了Ar,Kr,Xe和CO_2的捕集,同时还报告了与N_2O,CH_4,CF_4,C_2H_6和SF_6有关的初步结果。已经使用了一系列技术来阐明新的富勒烯插层固体的结构和所捕集的气体本身。使用的主要技术包括红外吸收光谱(IR),X射线粉末衍射a(XRD),中子粉末衍射(NRD),透射电子显微镜(TEM)和热重分析(TGA)。

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