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Solvates of the fluorofullerenes C60F46 and C60F48 with aliphatic hydrocarbons

机译:氟富勒烯C60F46和C60F48与脂族烃的溶剂

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The binary systems fluorofullerene-aliphatic hydrocarbon with normal structure were studied. The fluorofullerenes C60F46 and C60F48 were found to form molecular solvates with n-pentane, n-hexane, n-heptane, n-nonane, n-decane and n-undecane. Thermal gravimetry was used to estimate the mole composition of the solvates, differential scanning calorimetry - the dynamics of their decomposition and X-ray powder diffraction - the crystal structure of the solvates. The solubility of C60F48 in alkanes at room temperature was determined and dependence of solubility upon properties of solvates was shown. [References: 5]
机译:研究了具有正常结构的二元体系氟富勒烯-脂肪烃。发现氟富勒烯C60F46和C60F48与正戊烷,正己烷,正庚烷,正壬烷,正癸烷和正十一烷形成分子溶剂化物。使用热重分析法来估计溶剂化物的摩尔组成,差示扫描量热法-它们的分解动力学和X射线粉末衍射-溶剂化物的晶体结构。测定了C 60 F 48在室温下在烷烃中的溶解度,并显示了溶解度对溶剂化物性质的依赖性。 [参考:5]

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