Polymerization of 1,3-Butadiene with Several Catalytic Systems Based on Neodymium or Lithium in Presence of Ionic Liquids

Ramón Díaz de León; María Teresa Alonso Córdova; Francisco Javier Enríquez Medrano; José Díaz Elizondo; Odilia Pérez Camacho; Aldo Romo Quiroz; Rosa Idalia Narro Céspedes; Adali Casta?eda Facio

首页> 外文期刊>Macromolecular symposia >Polymerization of 1,3-Butadiene with Several Catalytic Systems Based on Neodymium or Lithium in Presence of Ionic Liquids

【24h】

Polymerization of 1,3-Butadiene with Several Catalytic Systems Based on Neodymium or Lithium in Presence of Ionic Liquids

机译：离子液体存在下基于钕或锂的几种催化体系聚合1,3-丁二烯

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The anionic and Ziegler-Natta polymerizations of 1,3-butadiene initiated with n-BuLi and NdV/TIBA/DEAC respectively were carried out in presence of ionic liquids and cyclohexane as solvent in both cases. Polybutadienes obtained were characterized by SEC, NMR and DSC techniques and results were compared with polybutadienes synthesized under similar conditions but in absence of ionic liquids. In all cases, the presence of ionic liquids caused a decrease in the reaction exothermal and also a diminution in the molecular weight distribution. The ionic liquids increased the microstructure cis-1,4 in both kind of polymerizations, and promotes a shift towards lower temperatures in the glass-transition temperature.

机译：在两种情况下，分别在离子液体和环己烷作为溶剂存在下，分别用n-BuLi和NdV / TIBA / DEAC引发的1,3-丁二烯的阴离子和Ziegler-Natta聚合反应。通过SEC，NMR和DSC技术对获得的聚丁二烯进行表征，并将结果与在类似条件下但不存在离子液体的情况下合成的聚丁二烯进行比较。在所有情况下，离子液体的存在都会引起反应放热的降低，以及分子量分布的减小。离子液体在两种聚合反应中均增加了微观结构cis-1,4，并促进了玻璃化转变温度向较低温度的转变。

著录项

来源
《Macromolecular symposia》 |2013年第1期|共9页
作者
Ramón Díaz de León; María Teresa Alonso Córdova; Francisco Javier Enríquez Medrano; José Díaz Elizondo; Odilia Pérez Camacho; Aldo Romo Quiroz; Rosa Idalia Narro Céspedes; Adali Casta?eda Facio;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类高分子化学（高聚物）;
关键词
1; 3-butadiene; anionic and Ziegler-Natta polymerizations; ionic liquids;

机译：1;3-丁二烯;阴离子和齐格勒-纳塔聚合;离子液体;

相似文献

外文文献
中文文献
专利

1. Polymerization of 1,3-Butadiene with Several Catalytic Systems Based on Neodymium or Lithium in Presence of Ionic Liquids [J] . Ramón Díaz de León, María Teresa Alonso Córdova, Francisco Javier Enríquez Medrano, Macromolecular symposia . 2013,第1期

机译：离子液体存在下基于钕或锂的几种催化体系聚合1,3-丁二烯
2. Ethene/1,3-Butadiene Copolymerization in the Presence of rac-(CH_2-(3-tert-butyl-1-indenyl)_2ZrCl_2/MAO Catalytic System:Study of the Polymerization Mechanism by Using ~(13)C-Labeled 1,3-Butadiene [J] . Stefania Pragliola, Chiara Costabile, Mariateresa Magrino, Macromolecules . 2004,第1期

机译：rac-（CH_2-（3-叔丁基-1-茚基）_2ZrCl_2 / MAO催化体系下的乙烯/ 1,3-丁二烯共聚反应：〜（13）C标记的聚合机理研究1， 3-丁二烯
3. A comparison of neodymium versatate, neodymium neopentanolate and neodymium bis(2-ethylhexyl)phosphate in ternary Ziegler type catalyst systems with regard to their impact on the polymerization of 1,3-butadiene [J] . Friebe L, Nuyken O, Obrecht W Journal of Macromolecular Science. Pure and Applied Chemistry . 2005,第7期

机译：齐格勒三元催化剂体系中叔碳酸钕，新戊醇钕和双（2-乙基己基）磷酸钕对1,3-丁二烯聚合反应的影响比较
4. Polymerization of 1,3-Butadiene with Several Catalytic Systems Based on Neodymium or Lithium in Presence of Ionic Liquids [C] . Ramon Daz de Leon, Mara Teresa Alonso Cordova, Francisco Javier Enrquez Medrano US-Mexico Symposium on Advances in Polymer Sxience-MACROMEX . 2013

机译：基于钕或锂基于离子液体的钕或锂的几种催化系统聚合
5. Chromium and Neodymium Complexes of bis-Phosphinimine Pincer Ligands and Their Behaviour in 1,3-Butadiene Polymerization. [D] . Resanovic, Sanja. 2011

机译：双膦亚胺钳配体的铬和钕配合物及其在1,3-丁二烯聚合中的行为。
6. UV-Cured Poly(Siloxane-Urethane)-Based Polymer Composite Materials for Lithium Ion Batteries—The Effect of Modification with Ionic Liquids [O] . Janusz Kozakiewicz, Jarosław Przybylski, Bartosz Hamankiewicz, 2020

机译：用于锂离子电池的UV固化聚（硅氧烷 - 氨基甲酸酯）基于聚合物复合材料 - 改性与离子液体的影响
7. Estudo da polimerização de 1,3-butadieno com sistemas catalíticos à base de neodímio Study of 1,3-butadiene polymerization by catalyst systems based on neodymium [O] . Luciana A. Fraga, Maria Inês B. Tavares, Fernanda M. B. Coutinho, 2003

机译：基于钕的催化体系对1,3-丁二烯聚合反应的研究基于钕的催化体系对1,3-丁二烯聚合反应的研究
8. Stereoregularity in Ziegler-Natta and Anionic Polymerization of 2-((Trimethylsilyl)methyl)-1,3-Butadiene. Protodesilation of cis-1,4-Poly(2-((trimethylsilyl)methyl)-1,3-butadiene) [R] . Ding, Y. X., Weber, W. P. 1988

机译：Ziegler-Natta中的立体规整性和2 - （（三甲基甲硅烷基）甲基）-1,3-丁二烯的阴离子聚合。顺式-1,4-聚（2 - （（三甲基甲硅烷基）甲基）-1,3-丁二烯的原始取代）

Polymerization of 1,3-Butadiene with Several Catalytic Systems Based on Neodymium or Lithium in Presence of Ionic Liquids

摘要

著录项

相似文献

相关主题

期刊订阅