Volumetric changes of randomly crosslinked model networks

Horstermann H; Hentschke R

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Volumetric changes of randomly crosslinked model networks

机译：随机交联模型网络的体积变化

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Equilibrium P-V-T properties of randomly crosslinked amorphous polymer networks are modeled via molecular dynamics simulation for connectivity ratios between 1.0 and 1.5. The relation between connectivity ratio and network shrinkage is studied over a wide range of temperatures and pressures. The simulation results are compared to a mean-field Flory-Huggins lattice model.

机译：随机交联的无定形聚合物网络的平衡P-V-T特性通过分子动力学模拟在1.0和1.5之间的连接比建模。在广泛的温度和压力范围内研究了连接率与网络收缩之间的关系。将模拟结果与平均场Flory-Huggins晶格模型进行比较。

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《Macromolecular theory and simulations》 |2007年第4期|共5页
作者
Horstermann H; Hentschke R;
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正文语种 eng
中图分类高分子化学（高聚物）;
关键词
polymer networks; molecular dynamics; lattice models; volume shrinkage; MONTE-CARLO-SIMULATION; MOLECULAR-DYNAMICS; POLYMER NETWORKS; GELS; BEHAVIOR; SOLVENT;

机译：聚合物网络分子动力学晶格模型体积收缩蒙特卡罗模拟分子动力学聚合物网络凝胶行为溶剂;

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1. Volumetric changes of randomly crosslinked model networks [J] . Horstermann H, Hentschke R Macromolecular theory and simulations . 2007,第4期

机译：随机交联模型网络的体积变化
2. Rheological behaviors of randomly crosslinked low density polyethylene, its gel network [J] . Zhang X., Yang H., Song Y., Polymer: The International Journal for the Science and Technology of Polymers . 2012,第14期

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3. RANDOM NETWORKS OF CROSSLINKED MANIFOLDS [J] . Roos C., Goldbart PM., Zippelius A. Journal of Physics, A. Mathematical and General: A Europhysics Journal . 1997,第6期

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4. MOLECULAR MODELING OF ELASTIC AND PHOTOELASTIC RELATIONSHIPS FOR CROSSLINKED POLYMER NETWORKS: A STATISTICAL SEGMENT APPROACH [C] . Hemant Nanavati, Prashant Desai, A.S.Abhiraman Plastics Bridging the Millennia . 1999

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Volumetric changes of randomly crosslinked model networks

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