Self-Assembly of Rod-Like Copolymers into Monolayers: A Simple Theoretical Estimate of Molecular Recognition Quality

Berezkin AV; Lazutin AA

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Self-Assembly of Rod-Like Copolymers into Monolayers: A Simple Theoretical Estimate of Molecular Recognition Quality

机译：棒状共聚物自组装成单层：分子识别质量的简单理论估计。

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A discrete model of a monolayer, consisting of identical rod-like copolymer molecules, is suggested. The influence of the copolymer's composition and sequence on its self-assembly was studied. Thermodynamic quantities of monolayers were calculated. It is shown that the system undergoes an "order-disorder" transition upon temperature increase. The most regular monolayers are formed by copolymers with quasi-random sequences. Nevertheless, the monomer composition of such "good" sequences can vary over a wide range. It is shown that homopolymers, copolymers with a predominance of one-type monomer units and copolymers consisting of a small number of large blocks have a reduced ability to self-assembly.

机译：建议由相同的棒状共聚物分子组成的单层离散模型。研究了共聚物的组成和顺序对其自组装的影响。计算了单层的热力学量。结果表明，随着温度的升高，系统会经历“有序-无序”过渡。最规则的单层是由具有准随机序列的共聚物形成的。然而，这种“良好”序列的单体组成可以在很宽的范围内变化。结果表明，均聚物，以一种单体单元为主的共聚物和由少量大嵌段组成的共聚物的自组装能力降低。

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《Macromolecular theory and simulations》 |2008年第7期|共11页
作者
Berezkin AV; Lazutin AA;
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原文格式 PDF
正文语种 eng
中图分类高分子化学（高聚物）;
关键词
monolayer; influence; homopolymers;

机译：单层;影响;均聚物;

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1. Self-Assembly of Rod-Like Copolymers into Monolayers: A Simple Theoretical Estimate of Molecular Recognition Quality [J] . Berezkin AV, Lazutin AA Macromolecular theory and simulations . 2008,第7期

机译：棒状共聚物自组装成单层：分子识别质量的简单理论估计。
2. Molecular Recognition in Solutions of Rod-Like Copolymers with Two Different Sequences [J] . Lazutin AA, Berezkin AV Macromolecular theory and simulations . 2009,第6期

机译：两种不同序列的棒状共聚物溶液中的分子识别
3. The Link Between Self-Assembly and Molecular Conformation of Amphiphilic Block Copolymers Monolayers at the Air/Water Interface: The Spreading Parameter [J] . Destri Giovanni Li, Malfatti Gasperini Antonio A., Konovalov Oleg Langmuir: The ACS Journal of Surfaces and Colloids . 2015,第32期

机译：两性嵌段共聚物单分子在空气/水界面的自组装与分子构象之间的联系：传播参数
4. Block Copolymer Self-assembly on Ethylene Glycol (EG) Self-assembled Monolayer (SAM) for Nanofabrication [C] . Dipu Borah, Sozaraj Rasappa, Barbara Kosmala, Materials Research Society Meeting . 2012

机译：嵌段共聚物自组装在乙二醇（例如）自组装单层（SAM）上用于纳米制备
5. Supramolecular chemistry: Molecular recognition and self-assembly using a versatile molecular cleft. [D] . Goshe, Andrew Joseph. 2003

机译：超分子化学：使用通用分子裂隙的分子识别和自组装。
6. Supramolecular Chemistry And Self-assembly Special Feature: Metal ion recognition and molecular templating inself-assembled monolayers of cyclic and acyclic polyethers [O] . Maria Ángeles Herranz, Barbara Colonna, Luis Echegoyen 2002

机译：超分子化学和自组装特征：金属离子识别和分子模板环状和无环聚醚的自组装单层
7. Templating Conducting Polymers via Self-Assembly of Block Copolymers and Supramolecular Recognition [O] . -1

机译：通过嵌段共聚物的自组装和超分子识别来模板传导聚合物
8. Synthesis and Characterization of Simple Self-Assembling, Nanoporous Monolayer Assemblies: A New Strategy for Molecular Recognition. [R] . Chailapakul, O., Crooks, R. M. 1992

机译：简单自组装纳米多孔单层组件的合成与表征：一种新的分子识别策略。

Self-Assembly of Rod-Like Copolymers into Monolayers: A Simple Theoretical Estimate of Molecular Recognition Quality

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