On Narrowing Chain-length Distributions in Ideally Dispersed Polymerization Systems

Ryszard Szymanski; Stanislaw Sosnowski

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On Narrowing Chain-length Distributions in Ideally Dispersed Polymerization Systems

机译：理想分散聚合体系中窄链长分布的研究

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Theoretical considerations and Monte Carlo simulations prove that small size of droplets narrows dispersity of chains in both chain and step polymerizations. Equations describing the chains lengths distribution in living polymerization carried out in nano-droplets are derived, proving to be the binomial distribution function. The effect of lowering of polymer dispersity in irreversible polycondensation is predicted as well.

机译：理论上的考虑和蒙特卡洛模拟证明，液滴的小尺寸会缩小链聚合和分步聚合中链的分散性。推导了描述在纳米液滴中进行的活性聚合中链长分布的方程，证明是二项分布函数。还预测了不可逆缩聚中降低聚合物分散性的效果。

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《Macromolecular theory and simulations》 |2014年第9期|共5页
作者
Ryszard Szymanski; Stanislaw Sosnowski;
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正文语种 eng
中图分类高分子化学（高聚物）;
关键词
dispersions; living polymerization; Monte Carlo simulation; molecular weight distribution; step-growth polymerization;

机译：分散体;活性聚合;蒙特卡洛模拟;分子量分布;逐步增长聚合;

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专利

1. On Narrowing Chain-length Distributions in Ideally Dispersed Polymerization Systems [J] . Ryszard Szymanski, Stanislaw Sosnowski Macromolecular theory and simulations . 2014,第9期

机译：理想分散聚合体系中窄链长分布的研究
2. Chain-length distributions and distribution coefficients in binary polymer blends [J] . Olaj OF., Zifferer G., Petrik T. Macromolecular theory and simulations . 1998,第6期

机译：二元聚合物共混物中链长分布和分布系数
3. Highly Dispersed Polymer Suspensions with a Narrow Particle Size Distribution for Biotechnology [J] . D.B. Adikanova, G.Zh. Yeligbaeva, I.A. Gritskova, Research Journal of Biological Sciences . 2015,第3期

机译：用于生物技术的具有窄粒径分布的高度分散的聚合物悬浮液
4. Motne Carlo simulation of kinetics and chain-length distribution in radical polymerization [C] . International symposium on polymer physics(PP'2002) . 2002

机译：自由基聚合反应动力学和链长分布的蒙特卡罗模拟
5. Preparation of Polymer Nanoparticles by Ring Opening Metathesis Polymerization in Aqueous Dispersed Systems with Water-Soluble Ruthenium-based Catalyst. [D] . Zhu, Chunyang. 2016

机译：水溶性钌基催化剂在水分散体系中通过开环复分解聚合制备聚合物纳米粒子。
6. A Strategy for Control of Random Copolymerization of Lactide and Glycolide: Application to Synthesis of PEG-b-PLGA Block Polymers Having Narrow Dispersity [O] . Haitao Qian, Adam R. Wohl, Jordan T. Crow, -1

机译：一个战略丙交酯的随机共聚控制和乙：以pEG-B-pLGa嵌段聚合物的合成具有窄分散度应用
7. A Strategy for Control of “Random” Copolymerization of Lactide and Glycolide: Application to Synthesis of PEG-b-PLGA Block Polymers Having Narrow Dispersity [O] . Haitao Qian, Adam R. Wohl, Jordan T. Crow, 2011

机译：一种控制“随机”丙交酯和乙酰基共聚的策略：应用于具有窄分散性的PEG-B-PLGA嵌段聚合物的应用
8. Monte Carlo Simulation of Kinetics and Chain-Length Distribution in Radical Polymerization. [R] . Lu, J. M., Zhang, H., Yang, Y. 1994

机译：蒙特卡罗模拟自由基聚合反应动力学和链长分布。

On Narrowing Chain-length Distributions in Ideally Dispersed Polymerization Systems

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