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首页> 外文期刊>Materials at High Temperatures >Haematite and chromia dissolution in the zirconia matrix during thermal oxidation of Laves-phases gamma-Zr(Fe,Cr)_2 on ZircaIoy-4
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Haematite and chromia dissolution in the zirconia matrix during thermal oxidation of Laves-phases gamma-Zr(Fe,Cr)_2 on ZircaIoy-4

机译:ZircaIoy-4上Laves相gamma-Zr(Fe,Cr)_2热氧化过程中氧化锆基体中的赤铁矿和氧化铬溶解

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摘要

The life time of the Zircaloy-4 alloy is linked to the role that intermetallic particles play during the growth of the zirconia scale. In the present work, a photoelectrochemical technique (PEC), has been used to study the phenomena of oxidation of intermetallic particles but also of dissolution of thermal oxidised particles. Both phenomena have been addressed in the literature and studied in particular with TEM; in this work, they were clearly imaged by photoelectrochemical microscopy at a mesoscopic view. Our results do contribute to a better understanding of the major impact that intermetallic precipitates could have on the oxidation rate.
机译:Zircaloy-4合金的使用寿命与氧化锆垢生长过程中金属间颗粒的作用有关。在目前的工作中,已使用光电化学技术(PEC)研究金属间颗粒的氧化现象以及热氧化颗粒的溶解现象。两种现象都在文献中得到了解决,尤其是在TEM中进行了研究。在这项工作中,它们通过光电化学显微镜在介观视图下清晰地成像。我们的结果确实有助于更好地了解金属间沉淀物可能对氧化速率的主要影响。

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