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Effect of specimen thickness on chromia scaling of Ni25Cr in N-2-O-2-H2O test gases at 1000 degrees C

机译:试样厚度对1000°C下N-2-O-2-H2O测试气体中Ni25Cr的色度标度的影响

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摘要

The isothermal oxidation behaviour of a Ni25Cr model alloy was studied using specimens of different thicknesses at 1000 degrees C in dry and wet N-2-1%O-2. The oxidation mechanisms were evaluated using thermogravimetry and SEM/electron backscatter diffraction analyses of oxide scale cross-sections. The oxidation rates decreased with increasing specimen thickness and increasing water vapour additions in the gas. The findings can be explained by considering the effect of H-defects and in-scale stress state on point defect concentrations in the chromia lattice.
机译:使用不同厚度的样品在干燥和潮湿的N-2-1%O-2中于1000摄氏度下研究了Ni25Cr模型合金的等温氧化行为。使用热重分析法和SEM /电子背散射衍射分析氧化皮横截面来评估氧化机理。氧化速率随样品厚度的增加和气体中水蒸气的添加而降低。可以通过考虑H缺陷和刻度应力状态对氧化铬晶格中点缺陷浓度的影响来解释这些发现。

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