Preparation and characterization of a chemically modified electrode based on ferrocene-tethered beta-cyclodextrin self assembled monolayers

Favero G; Campanella L; DAnnibale A; Ferri T

首页> 外文期刊>Microchemical Journal: Devoted to the Application of Microtechniques in all Branches of Science >Preparation and characterization of a chemically modified electrode based on ferrocene-tethered beta-cyclodextrin self assembled monolayers

【24h】

Preparation and characterization of a chemically modified electrode based on ferrocene-tethered beta-cyclodextrin self assembled monolayers

机译：基于二茂铁束缚的β-环糊精自组装单分子膜的化学修饰电极的制备和表征

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

We report the preparation and characterisation of a microcristalline An electrode chemically modified with a self-assembled monolayer (SAM) of a beta-cyclodextrin (beta-CD) derivative having attached suitably spaced ferrocene (FC) redox centers. The per-6-thio-beta-CD (S-beta-CD), SAM was investigated by cyclic voltammetry (CV) by using ferrocyanide and ferrocene carboxylic acid (FCA) as electrochemical probes. The mediator-tethered electrode was obtained by attaching a previously prepared (by a S(N)2 reaction) FC derivative to secondary OH groups of beta-CD, self-assembled on the Au surface. The obtained mediator-tethered electrode was characterised by CV, by using the above-mentioned electrochemical probes and (even if on a little extent) by microscopic ones. CV experiments in Fe(CN)(6)(-4) solutions provide evidence for the electron transfer (eT) mediating role played by FC centres tethered to beta-CD SAM, of importance in the perspective of realising oxygen-independent biosensors based on oxidase enzymes. (C) 2003 Elsevier B.V All rights reserved.

机译：我们报告了微晶的制备和表征。用自组装的单分子层（SAM）的β-环糊精（β-CD）衍生物进行化学修饰的电极，其具有适当间隔的二茂铁（FC）氧化还原中心。使用亚铁氰化物和二茂铁羧酸（FCA）作为电化学探针，通过循环伏安法（CV）研究了六硫代β-CD（S-β-CD）SAM。通过将预先制备的（通过S（N）2反应）FC衍生物附着到自组装在Au表面上的β-CD的仲OH基上获得介体连接的电极。所获得的介体束缚电极通过使用上述电化学探针的CV和（即使在很小程度上）通过微观探针进行CV表征。 Fe（CN）（6）（-4）解决方案中的CV实验提供了证据证明由FC中心束缚到β-CDSAM的电子传递（eT）介导的作用，这对于实现基于氧的非生物传感器至关重要氧化酶。（C）2003 Elsevier B.V保留所有权利。

著录项

来源
《Microchemical Journal: Devoted to the Application of Microtechniques in all Branches of Science》 |2004年第2期|共8页
作者
Favero G; Campanella L; DAnnibale A; Ferri T;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类定量分析（定量分析学）;
关键词
ferrocene-tethered; beta-cyclodextrin; reagentless bionsensor; chemically modified electrode; AMPEROMETRIC BIOSENSOR; GLUCOSE-OXIDASE; ACID-DERIVATIVES; ENZYME; COMPLEXES; MEDIATOR; SURFACE; FILMS;

机译：二茂铁束缚;β-环糊精;无试剂的仿生传感器;化学修饰的电极;安培生物传感器;葡萄糖氧化酶;酸衍生物;酶;络合物;介质;表面;薄膜;

相似文献

外文文献
中文文献
专利

1. Preparation and characterization of a chemically modified electrode based on ferrocene-tethered beta-cyclodextrin self assembled monolayers [J] . Favero G, Campanella L, DAnnibale A, Microchemical Journal: Devoted to the Application of Microtechniques in all Branches of Science . 2004,第1a2期

机译：基于二茂铁束缚的β-环糊精自组装单分子膜的化学修饰电极的制备和表征
2. Electrochemical and spectroscopic characterization of screen-printed gold-based electrodes modified with self-assembled monolayers and Tc85 protein [J] . Ferreira AAP, Fugivara CS, Barrozo S, Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2009,第2期

机译：自组装单层膜和Tc85蛋白修饰的丝网印刷金基电极的电化学和光谱表征
3. Preparation, characterization and application of alkanethiol self-assembled monolayers modified with tetrathiafulvalene and glucose oxidase at a gold disk electrode [J] . Susana Campuzano, Rocio Galvez, Maria Pedrero, Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2002,第1a2期

机译：金硫脲富瓦烯和葡萄糖氧化酶修饰的烷硫醇自组装单层膜的制备，表征及应用
4. PREPARATION, CHARACTERIZATION AND APPLICATION OF ALKANETHIOL SELF-ASSEMBLED MONOLAYERS MODIFIED WITH TETRATHIAFULVALENE AND GLUCOSE OXIDASE AT A GOLD DISK ELECTRODE [C] . Susana Campuzano, Rocio Galvez, Maria Pedrero, International Symposium on Chemical and Biological Sensors and Analytical Methods II, 2001 . 2001

机译：四硫代富勒戊烯和葡萄糖氧化酶修饰的烷基酚自组装单分子膜在金盘电极上的制备，表征和应用
5. Chemically modified electrodes with nanocatalysts and their layer-by-layer self-assembled nanothin films: Preparation, characterization and application. [D] . Wang, Bao Xing. 2001

机译：具有纳米催化剂的化学修饰电极及其逐层自组装纳米薄膜：制备，表征和应用。
6. An Electrochemical Immunosensor Based on a Self-Assembled Monolayer Modified Electrode for Label-Free Detection of α-Synuclein [O] . Chuang-Ye Ge, Md. Mahbubur Rahman, Wei Zhang, 2020

机译：基于自组装单层修饰电极的无标记α-突触核蛋白电化学免疫传感器
7. Short-time preparation and electrochemical properties of a single layer of tetraoctylammonium bromide capped Au nanoparticles on dithiol self-assembled monolayer-modified Au electrode [O] . Abraham John S., Sagara Takamasa 2009

机译：在二硫醇自组装单层改性au电极上单层四辛基溴化铵封端的au纳米粒子的短时制备和电化学性质
8. Nano-Engineered Electrochemical Sensors for Monitoring of Toxic Metals in Groundwater: Development of Novel Square Wave Anodic Stripping Voltammetry Electrodes Using Self Assembled Monolayers on Mesoporous Supports. [R] . Zemanian, T. S., Lin, Y. 2007

机译：用于监测地下水中有毒金属的纳米工程电化学传感器：在介孔载体上使用自组装单分子膜开发新型方波阳极溶出伏安法电极。

Preparation and characterization of a chemically modified electrode based on ferrocene-tethered beta-cyclodextrin self assembled monolayers

摘要

著录项

相似文献

相关主题

期刊订阅