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首页> 外文期刊>Minerals Engineering >ELECTROWINNING OF COBALT FROM ACIDIC SULPHATE SOLUTIONS--EFFECT OF CHLORIDE ION
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ELECTROWINNING OF COBALT FROM ACIDIC SULPHATE SOLUTIONS--EFFECT OF CHLORIDE ION

机译:酸性硫酸盐溶液中钴的电缠绕-氯离子的作用

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摘要

Cobalt electrowinning from acidic sulphate solution was carried out in the presence and absence of chloride ion in the electrolyte. The effect of current density, electrolyte flow rate and temperature on cobalt electrowinning was studied from pure cobalt sulphate solutions and solutions containing 2000 mg dm~(-3) chloride ion. It was found that presence of chloride ion did not have any significant effect on cobalt deposition potential, current efficiency and preferred crystal orientation of the electrowon cobalt. However, the surface morphology of the cobalt electrodeposits was affected quite strongly which may be attributed to the variation of the intensity of the crystal planes during the electrodeposition process.
机译:在电解液中存在和不存在氯离子的情况下,从酸性硫酸盐溶液中电解提取钴。从纯硫酸钴溶液和含2000 mg dm〜(-3)氯离子的溶液中研究了电流密度,电解质流速和温度对钴电解沉积的影响。已经发现,氯离子的存在对钴沉积电位,电流效率和电子离子钴的优选晶体取向没有任何显着影响。然而,钴电沉积物的表面形态受到相当大的影响,这可能归因于电沉积过程中晶面强度的变化。

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