Syntheses and Physical Properties of Ferrocene Derivatives (XVII) Crystal Structure of a Liquid Crystalline Ferrocene Derivative, 1, 1'-bis[5-[4-(4-methoxyphenoxycarbonyl)phenoxy] pentyloxycarbonyl]ferrocene

Naotake Nakamura; Takashi Okabe; Terumi Takahashi

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Syntheses and Physical Properties of Ferrocene Derivatives (XVII) Crystal Structure of a Liquid Crystalline Ferrocene Derivative, 1, 1'-bis[5-[4-(4-methoxyphenoxycarbonyl)phenoxy] pentyloxycarbonyl]ferrocene

机译：液晶二茂铁衍生物1，1'-双[5- [4- [4-（4-甲氧基苯氧基羰基）苯氧基]戊氧基羰基]二茂铁的二茂铁衍生物（XVII）的晶体结构的合成和物理性质

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The molecular and crystal structures of 1,1'-disubstituted ferrocene derivative, 1,1'-bis[5-[4-(4-methoxyphenoxycarbonyl)phenoxy]pentyloxycarbonyl]ferrocene (bMAF-5) were determined by X-ray diffraction method using a single crystal. This compound is a liquid crystalline one. As generally expected, the molecular feature is "S" shape in which the two substituents are present in the opposite directions. The -C_5H_(10)-chain introduced into the molecule as a flexible spacer includes two gauche conformations. The gauche conformation plays an important role to make a rod-like shape, which is favorable to show liquid crystallinity.

机译：通过X射线衍射法测定了1,1'-二取代的二茂铁衍生物1,1'-双[5- [4-（4-甲氧基苯氧基羰基）苯氧基]戊氧基羰基]二茂铁（bMAF-5）的分子和晶体结构使用单晶。该化合物是液晶化合物。如通常所预期的，分子特征是“ S”形，其中两个取代基以相反的方向存在。作为柔性间隔基引入分子中的-C_5H_（10）链包括两个gauche构象。乳脂状构象在形成棒状形状中起重要作用，这有利于显示液晶性。

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《Molecular crystals and liquid crystals》 |2005年第0期|共8页
作者
Naotake Nakamura; Takashi Okabe; Terumi Takahashi;
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正文语种 eng
中图分类晶体学;
关键词
1; 1'-disubstituted ferrocene derivative; crystal structure; ferrocene; liquid crystal;

机译：1;1'-二取代二茂铁衍生物;晶体结构;二茂铁;液晶;

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1. Syntheses and Physical Properties of Ferrocene Derivatives (XVII) Crystal Structure of a Liquid Crystalline Ferrocene Derivative, 1, 1'-bis[5-[4-(4-methoxyphenoxycarbonyl)phenoxy] pentyloxycarbonyl]ferrocene [J] . Naotake Nakamura, Takashi Okabe, Terumi Takahashi Molecular crystals and liquid crystals . 2005,第0期

机译：液晶二茂铁衍生物1，1'-双[5- [4- [4-（4-甲氧基苯氧基羰基）苯氧基]戊氧基羰基]二茂铁的二茂铁衍生物（XVII）的晶体结构的合成和物理性质
2. Synthesis and physical properties of ferrocene derivatives (XX): Crystal structure of a liquid-crystalline ferrocene derivative, 1,1 '-bis [9-[4-(4-methoxyphenoxycarbonyl)phenoxy]nonyloxycarbonyl]ferrocene [J] . Nakamura N, Nio T, Okabe T, Molecular crystals and liquid crystals . 2007,第0期

机译：二茂铁衍生物（XX）的合成和物理性质：液晶二茂铁衍生物1,1'-双[9- [4-（4-（4-甲氧基苯氧基羰基）苯氧基]壬基氧羰基]二茂铁的晶体结构
3. SYNTHESES AND PHYSICAL PROPERTIES OF FERROCENE DERIVATIVES (XVI): CRYSTAL STRUCTURE OF A LIQUID CRYSTALLINE FERROCENE DERIVATIVE, 5-[4-(4-METHOXYPHENOXYCARBONYL) PHENOXYCARBONYL] PENTYL 4-FERROCENYLBENZOATE [J] . Naotake Nakamura, Terumi Takahashi, Kenjiro Uno Molecular Crystals and Liquid Crystals Science and Technology, Section A. Molecular Crystals and Liquid Crystals . 2002,第0期

机译：二茂铁衍生物（XVI）的合成和物理性质：液态结晶二茂铁衍生物5- [4-（4-（羟甲基苯氧基羰基）苯氧基羰基]戊基4-戊烯基苯甲酸酯的晶体结构
4. Synthesis and physical properties of ferrocene derivatives XXIV: structural study of liquid crystalline mono-substituted ferrocene derivatives [C] . Naotake Nakamura, Kazuya Hiro, Kenjiro Uno Liquid crystals XIV . 2010

机译：二茂铁衍生物XXIV的合成和物理性质：液晶单取代二茂铁衍生物的结构研究
5. Synthesis and structure-property relationships of ferrocene-containing liquid crystals. [D] . Bhatt, Jayprakash C. 1991

机译：含二茂铁的液晶的合成及其结构-性质关系。
6. The Synthesis and Structures of 11′-Bis(sulfonyl)ferrocene Derivatives [O] . Kullapa Chanawanno, Cole Holstrom, Laura A. Crandall, -1

机译：11-双（磺酰基）二茂铁衍生物的合成与结构
7. Synthesis and physical properties of ferrocene derivatives. XXI. Crystal structure of a liquid crystalline ferrocene derivative, 1,1'-bis3-4-(4-methoxyphenoxycarbonyl)phenoxypropyloxycarbonylferrocene [O] . Takashi Okabe, Keisuke Nakazaki, Tsuyoshi Igaue, 2009

机译：二茂铁衍生物的合成与物理性质。 XXI。液晶二茂铁衍生物的晶体结构，1,1'-BIS 3- 4-甲氧基氧基羰基）苯氧基二茂铁
8. Ferrocene and ferrocene derivatives [R] . Mc Nutt, W. P., Pittman, C. V., Jr. 1966

机译：二茂铁和二茂铁衍生物

Syntheses and Physical Properties of Ferrocene Derivatives (XVII) Crystal Structure of a Liquid Crystalline Ferrocene Derivative, 1, 1'-bis[5-[4-(4-methoxyphenoxycarbonyl)phenoxy] pentyloxycarbonyl]ferrocene

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