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首页> 外文期刊>Molecular crystals and liquid crystals >Principle of maximum flow energy, a useful working hypothesis to approach ordering phenomena in fluids
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Principle of maximum flow energy, a useful working hypothesis to approach ordering phenomena in fluids

机译:最大流能原理,一种用于处理流体中有序现象的有用工作假设

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摘要

The hypothesis that the variation of energy with time and volume for real and/or imaginary exchange processes leads to a maximum is applied to various phenomena found with fluids, especially with liquid crystals. Reference is made to some qualitative regularities in the correlation of chemical structure and the thermodynamic stability of the thermotropic nematic phase, the enthalpy of the phase transition between fluid phases, the heuristically important finding of an exothermic transition from the nematic to the isotropic phase, a very distinct deuterium isotopic effect on the optical nonlinearity of a dye-doped nematic phase, and the additional hydrodynamic lifting force observed in technical slide bearings lubricated with isotropic oils containing mesogenic compounds. The relation of the suggested variation to the universally valid principle of least action and its applicability to irreversible processes are discussed.
机译:实数和/或虚数交换过程中能量随时间和体积的变化导致最大值的假说适用于在流体(尤其是液晶)中发现的各种现象。在化学结构和热致向列相的热力学稳定性的相关性,流体相之间的相变的焓,从向列相到各向同性相的放热跃迁的启发式重要发现中,参考了一些定性规律。氘同位素对染料掺杂的向列相的光学非线性有非常明显的影响,并且在用含介晶化合物的各向同性油润滑的工业滑动轴承中观察到了额外的流体动力提升力。讨论了建议的变化与最小作用的普遍有效原理之间的关系及其对不可逆过程的适用性。

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