Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)

Suckert S.; Werner J.; Jess I.Näther C.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II)

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Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II)

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The crystal structure of the title compound, Co(NCS)2(C2H3N)2(C12H9NO)2, consists of cobalt(II) cations that are octahedrally coordinated by the N atoms of two terminal thiocyanate anions, two acetonitrile molecules and two 4-benzoylpyridine ligands. The discrete complexes are located on centres of inversion. They are connected by weak intermolecular C—H⋯O and C—H⋯S hydrogen-bonding interactions between one of the pyridine H atoms and the carbonyl O atom, and between one of the methyl H atoms of the acetonitrile molecule and the thiocyanate S atoms into layers parallel to (101). No pronounced intermolecular interactions are observed between these layers.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第3期|365-368|共4页
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Suckert S.; Werner J.; Jess I.Näther C.;
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Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)

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Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II)