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首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of tetra­aqua­bis­(1,3-dimethyl-2,6-dioxo-7H-purin-7-ido-κN7)cobalt(II)
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Crystal structure of tetra­aqua­bis­(1,3-dimethyl-2,6-dioxo-7H-purin-7-ido-κN7)cobalt(II)

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摘要

The title complex, Co(C7H7N4O2)2(H2O)4, comprises mononuclear mol­ecules consisting of a CoII ion, two deprotonated theophylline ligands (systematic name: 1,3-dimethyl-7H-purine-2,6-dione) and four coordinating water mol­ecules. The CoII atom lies on an inversion centre and has a slightly distorted octa­hedral coordination environment, with two N atoms of two trans-oriented theophylline ligands and the O atoms of four water mol­ecules. An intra­molecular hydrogen bond stabilizes this conformation. A three-dimensional supra­molecular network structure is formed by inter­molecular O—H⋯O and O—H⋯N hydrogen bonds.

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