Block Copolymer Morphologies in Dye-Sensitized Solar Cells: Probing the Photovoltaic Structure-Function Relation

Crossland EJW; Nedelcu M; Ducati C; Ludwigs S; Hillmyer MA; Steiner U; Snaith HJ

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Block Copolymer Morphologies in Dye-Sensitized Solar Cells: Probing the Photovoltaic Structure-Function Relation

机译：染料敏化太阳能电池中的嵌段共聚物形态：探讨光伏结构与功能的关系

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We integrate mesostructured titania arrays into dye-sensitized solar cells by replicating ordered, oriented one-dimensional (1D) columnar and three-dimensional (3D) bicontinuous gyroid block copolymer phases. The solar cell performance, charge transport, and recombination are Investigated. We observe faster charge transport in 1D "wires" than through 3D gyroid arrays. However, owing to their structural instability, the surface area of the wire arrays is low, inhibiting the solar cell performance. The gyroid morphology, on the other hand, outperforms the current state-of-the-art mesoporous nanoparticle films.

机译：我们通过复制有序的，定向的一维（1D）柱状和三维（3D）双连续的回旋陀螺嵌段共聚物相，将介观二氧化钛阵列集成到染料敏化太阳能电池中。研究了太阳能电池的性能，电荷传输和复合。我们观察到一维“导线”中的电荷传输比通过3D陀螺阵列更快。然而，由于它们的结构不稳定性，线阵列的表面积低，从而抑制了太阳能电池的性能。另一方面，螺旋状形态优于当前的最新中孔纳米颗粒薄膜。

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《Nano letters》 |2009年第8期|共7页
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Crossland EJW; Nedelcu M; Ducati C; Ludwigs S; Hillmyer MA; Steiner U; Snaith HJ;
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1. Block Copolymer Morphologies in Dye-Sensitized Solar Cells: Probing the Photovoltaic Structure-Function Relation [J] . Crossland EJW, Nedelcu M, Ducati C, Nano letters . 2009,第8期

机译：染料敏化太阳能电池中的嵌段共聚物形态：探讨光伏结构与功能的关系
2. Chemically deposited blocking layers on FTO substrates: Effect of precursor concentration on photovoltaic performance of dye-sensitized solar cells [J] . Yoo B, Kim KJ, Bang SY, Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2010,第1期

机译：在FTO基板上化学沉积的阻挡层：前体浓度对染料敏化太阳能电池光伏性能的影响
3. Syntheses and photovoltaic properties of polymeric sensitizers using thiophene-based copolymer derivatives for dye-sensitized solar cells [J] . Lee S.-M., Lee S.-B., Kim K.-H., Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion . 2011,第1期

机译：使用基于噻吩的共聚物衍生物的聚合物敏化剂的合成和光电性能，用于染料敏化太阳能电池
4. Dye-sensitized solar cells using localized surface plasmon of gold and silver nanoparticles with comb-shaped block copolymer [C] . Mikio Enomoto, Katsuhiko Taniguchi, Manabu Ihara Symposium on semiconductor electrolyte interface and photoelectrochemistry . 2010

机译：使用具有梳形嵌段共聚物的金和银纳米粒子的局部表面等离子体的染料敏化太阳能电池
5. Spectroscopic and electrochemical characterization of dye-sensitized, multilayered, and molecular photovoltaic solar cells. [D] . Massari, Aaron Michael. 2004

机译：染料敏化，多层和分子光伏太阳能电池的光谱和电化学表征。
6. Effect of ZnO Nanoparticles Coating Layers on Top of ZnO Nanowires for Morphological Optical and Photovoltaic Properties of Dye-Sensitized Solar Cells [O] . Muhammad Saleem, W. A. Farooq, M. I. Khan, 2019

机译：ZnO纳米线顶部的ZnO纳米颗粒涂层对染料敏化太阳能电池的形态光学和光伏特性的影响
7. Blocking Layers Deposited on TCO Substrate and Their Effects on Photovoltaic Properties in Dye-Sensitized Solar Cells [O] . Beom-Hin Yoo, Kyung-Kon Kim, Doh-Kwon Lee, 2011

机译：沉积在TCO基材上的阻挡层及其对染料敏化太阳能电池的光伏性能的影响

Block Copolymer Morphologies in Dye-Sensitized Solar Cells: Probing the Photovoltaic Structure-Function Relation

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