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Dynamics of carbon nanotube growth from fullerenes

机译:富勒烯碳纳米管生长的动力学

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The growth of double-walled carbon nanotubes from peapods was studied. The transformation was monitored by the decrease of fullerene Raman lines, the growth of inner tube Raman lines, and the development of X-ray diffraction patterns. A visual check of the growth process by HRTEM provided additional information. From the difference in time constants for the bleaching of fullerene Raman lines and for the growth of nanotube Raman lines, the existence of an intermediate phase was concluded that was eventually observed in X-ray diffraction and HRTEM. Time constants for the growth of large diameter inner tubes were up to a factor two larger than for small diameter inner tubes. The results fully support the fullerene coalescence growth model triggered by Stone-Wales transformations.
机译:研究了豌豆足双壁碳纳米管的生长。通过富勒烯拉曼线的减少,内管拉曼线的生长以及X射线衍射图的发展来监测转变。 HRTEM对生长过程的目视检查提供了更多信息。从富勒烯拉曼线的漂白和纳米管拉曼线的生长时间常数的差异,可以得出中间相的存在,该中间相最终在X射线衍射和HRTEM中观察到。大直径内管生长的时间常数比小直径内管增长的时间常数大两倍。结果完全支持了Stone-Wales转换触发的富勒烯结合生长模型。

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