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Photoinduced charge transfer and efficient solar energy conversion in a blend of a red polyfluorene copolymer with CdSe nanoparticles

机译:红色聚芴共聚物与CdSe纳米粒子的混合物中的光诱导电荷转移和高效太阳能转化

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摘要

We present measurements of charge transfer and the photovoltaic effect in a blend of the alternating polyfluorene copolymer poly(2,7-(9,9-dioctyl-fluorene)-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)) with branched CdSe nanoparticles. Quasi-steady-state photoinduced absorption measurements identified a long-lived charged species that formed after photoexcitation at room temperature. Photovoltaic devices based on this blend system showed a spectral response extending to 650 nm and gave a solar power conversion efficiency of 2.4% under Air Mass 1.5 Global (AM1.5G) conditions.
机译:我们提出了交替聚芴共聚物聚(2,7-(9,9-二辛基-芴)-alt-5,5-(4',7'-di-2)的混合物中电荷转移和光伏效应的测量结果-噻吩基2',1',3'-苯并噻二唑))和支链CdSe纳米粒子。准稳态光诱导吸收测量确定了在室温下光激发后形成的长寿命带电物种。基于这种共混体系的光伏设备显示光谱响应扩展到650 nm,在空气质量1.5 Global(AM1.5G)条件下的太阳能转换效率为2.4%。

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