Phase diagrams of small particles of binary systems: a theoretical approach

M. Wautelet; J. P. Dauchot

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Phase diagrams of small particles of binary systems: a theoretical approach

机译：二元系统小颗粒的相图：一种理论方法

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The phase diagrams of small particles (withdiameters in the nm range) are studied theoretically. In the limitwhere thermodynamical arguments remain valid, it is deduced thatthe phase diagram of small particles is a function of their size. Forthe case of ideal solutions, it is shown that the lens-shaped solidus-liquidus curves are shifted to lower temperatures between thehighest bulk melting point and the lowest melting point of theparticle, the relative concentrations of the solid and liquid phasesare different in the particle and bulk material.

机译：理论上研究了小颗粒（直径在nm范围内）的相图。在热力学论点仍然有效的极限下，推论出小颗粒的相图是其尺寸的函数。对于理想解的情况，表明透镜状的固-液相线曲线在颗粒的最高本体熔点和最低熔点之间移至较低的温度，颗粒中固相和液相的相对浓度不同。散装材料。

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《Nanotechnology》 |2000年第1期|共4页
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M. Wautelet; J. P. Dauchot;
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8. Phase Equilibria Investigation of Binary, Ternary, and Higher Order Systems. Part I. The Phase Diagrams of The Systems Ti-Nb-C, Ti-Ta-C, and Ti-Mo-C [R] . Rudy, E. 1970

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Phase diagrams of small particles of binary systems: a theoretical approach

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